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Materials Discovery by Flux Crystal Growth : = Synthesis, Structure Determination, Magnetic, and Optical Properties of Complex Oxides, Oxychlorides, and Oxyfluorides.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Materials Discovery by Flux Crystal Growth :/
Reminder of title:	Synthesis, Structure Determination, Magnetic, and Optical Properties of Complex Oxides, Oxychlorides, and Oxyfluorides.
Author:	Carone, Darren Andrew.
Description:	1 online resource (147 pages)
Notes:	Source: Dissertations Abstracts International, Volume: 84-05, Section: B.
Contained By:	Dissertations Abstracts International84-05B.
Subject:	Inorganic chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=29206841click for full text (PQDT)
ISBN:	9798352955482

Materials Discovery by Flux Crystal Growth : = Synthesis, Structure Determination, Magnetic, and Optical Properties of Complex Oxides, Oxychlorides, and Oxyfluorides.
Carone, Darren Andrew.

Materials Discovery by Flux Crystal Growth :Synthesis, Structure Determination, Magnetic, and Optical Properties of Complex Oxides, Oxychlorides, and Oxyfluorides. - 1 online resource (147 pages)

Source: Dissertations Abstracts International, Volume: 84-05, Section: B.

Thesis (Ph.D.)--University of South Carolina, 2022.

Includes bibliographical references

Exploratory crystal growth has proven to be a successful technique in the synthesis of new compounds with desired properties. This method is very versatile and has various iterations, but results described herein were obtained through flux growth at high temperatures utilizing mixed alkali halide salts. The tunability of these reactions with respect to reactant ratios, reaction temperature, heating/cooling rates, metal precursors, and choice of flux allow for the exploration of phase spaces between a combination of elements and observation of significantly different products and/or structure types from minor tweaks.Most of the research presented in this dissertation describes results that were attained while exploring phase spaces involving silicates and germanates paired with transition metals, striving for colorless framework materials. In this thesis the synthesis, crystal structure determination, and physical property measurements of La8.64W6O30.45Cl, Ce8.64W5.74O30Cl, Ln8.33W6O30Cl (Ln = Pr, Nd), [(Rb6F)(Rb4F)][Ge14O32], [(Rb6F)(Rb3.1Co0.9F0.96)][Co3.8Ge10.2O30F2], Rb2Cu3Ge5O14, Cs2Cu3Ge5O14, Cs7Cu2Ge11O27F, [(Cs6F)(Cs3AgF)][Ge12Mn2O32], Rb4Ta2Si8O23, and Rb4Ge5O9F6:Nb. These new compositions have been studied for magnetic and optical properties, including fluorescence, fluorescence quantum yield, and radioluminescence, when practical.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2023

Mode of access: World Wide Web

ISBN: 9798352955482Subjects--Topical Terms:

3173556
Inorganic chemistry.
Subjects--Index Terms:

Flux crystal growthIndex Terms--Genre/Form:

542853
Electronic books.

Materials Discovery by Flux Crystal Growth : = Synthesis, Structure Determination, Magnetic, and Optical Properties of Complex Oxides, Oxychlorides, and Oxyfluorides.
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502 $a Thesis (Ph.D.)--University of South Carolina, 2022.
504 $a Includes bibliographical references
520 $a Exploratory crystal growth has proven to be a successful technique in the synthesis of new compounds with desired properties. This method is very versatile and has various iterations, but results described herein were obtained through flux growth at high temperatures utilizing mixed alkali halide salts. The tunability of these reactions with respect to reactant ratios, reaction temperature, heating/cooling rates, metal precursors, and choice of flux allow for the exploration of phase spaces between a combination of elements and observation of significantly different products and/or structure types from minor tweaks.Most of the research presented in this dissertation describes results that were attained while exploring phase spaces involving silicates and germanates paired with transition metals, striving for colorless framework materials. In this thesis the synthesis, crystal structure determination, and physical property measurements of La8.64W6O30.45Cl, Ce8.64W5.74O30Cl, Ln8.33W6O30Cl (Ln = Pr, Nd), [(Rb6F)(Rb4F)][Ge14O32], [(Rb6F)(Rb3.1Co0.9F0.96)][Co3.8Ge10.2O30F2], Rb2Cu3Ge5O14, Cs2Cu3Ge5O14, Cs7Cu2Ge11O27F, [(Cs6F)(Cs3AgF)][Ge12Mn2O32], Rb4Ta2Si8O23, and Rb4Ge5O9F6:Nb. These new compositions have been studied for magnetic and optical properties, including fluorescence, fluorescence quantum yield, and radioluminescence, when practical.
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653 $a Materials discovery
653 $a Oxyfluorides
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710 2 $a University of South Carolina. $b Chemistry. $3 1020774
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