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Metal-Organic Framework (MOF) Assisted Ion Conduction in Solid Polymer Electrolytes for Application in Lithium-Ion Batteries.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Metal-Organic Framework (MOF) Assisted Ion Conduction in Solid Polymer Electrolytes for Application in Lithium-Ion Batteries./
Author:	Zerin, Nagma.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2021,
Description:	178 p.
Notes:	Source: Dissertations Abstracts International, Volume: 83-03, Section: B.
Contained By:	Dissertations Abstracts International83-03B.
Subject:	Polymers. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28841678
ISBN:	9798460448548

Metal-Organic Framework (MOF) Assisted Ion Conduction in Solid Polymer Electrolytes for Application in Lithium-Ion Batteries.
Zerin, Nagma.

Metal-Organic Framework (MOF) Assisted Ion Conduction in Solid Polymer Electrolytes for Application in Lithium-Ion Batteries. - Ann Arbor : ProQuest Dissertations & Theses, 2021 - 178 p.

Source: Dissertations Abstracts International, Volume: 83-03, Section: B.

Thesis (Ph.D.)--The Pennsylvania State University, 2021.

This item must not be sold to any third party vendors.

Solid polymer electrolytes (SPEs) are safer and cleaner alternatives to the flammable organic liquid electrolytes used in rechargeable lithium-ion batteries. Due to having the potential to tune stiffness, SPEs can prevent dendrite formation while being used with the lithium-metal anode of high energy density. The most common SPE is polyethylene oxide (PEO) dissolving a lithium salt (e.g., LiClO4). PEO is popular due to its ability to dissolve lithium salts easily and commercial availability at a reasonable cost. However, these electrolytes have very low ionic conductivity at room temperature (less than 10.

ISBN: 9798460448548Subjects--Topical Terms:

535398
Polymers.
Subjects--Index Terms:

Lithium ion batteries

Metal-Organic Framework (MOF) Assisted Ion Conduction in Solid Polymer Electrolytes for Application in Lithium-Ion Batteries.
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100 1 $a Zerin, Nagma. $3 3683766
245 1 0 $a Metal-Organic Framework (MOF) Assisted Ion Conduction in Solid Polymer Electrolytes for Application in Lithium-Ion Batteries.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2021
300 $a 178 p.
500 $a Source: Dissertations Abstracts International, Volume: 83-03, Section: B.
500 $a Advisor: Maranas, Janna.
502 $a Thesis (Ph.D.)--The Pennsylvania State University, 2021.
506 $a This item must not be sold to any third party vendors.
520 $a Solid polymer electrolytes (SPEs) are safer and cleaner alternatives to the flammable organic liquid electrolytes used in rechargeable lithium-ion batteries. Due to having the potential to tune stiffness, SPEs can prevent dendrite formation while being used with the lithium-metal anode of high energy density. The most common SPE is polyethylene oxide (PEO) dissolving a lithium salt (e.g., LiClO4). PEO is popular due to its ability to dissolve lithium salts easily and commercial availability at a reasonable cost. However, these electrolytes have very low ionic conductivity at room temperature (less than 10.
520 $a -5 S/cm), which does not meet the performance demands for practical battery applications. It is commonly believed that lithium-ion conduction in PEO-based electrolytes only depends on polymer segmental motion in amorphous regions. Thus, to increase polymer mobility associated conductivity, a considerable amount of research is focused on lowering the glass transition temperature (Tg) of SPEs. However, this approach compromises the SPE stiffness, which makes it incompatible with the lithium-metal anode. Crystalline solid polymer electrolytes, commonly known as polymer-salt co-crystals, are promising alternatives to dissociate conductivity from polymer mobility and increase stiffness. Unfortunately, these crystals are poor ion conductors on their own. There are not many studies that attempt to increase conduction through polymer-salt co-crystals. This research aims to improve conduction through these crystals and understand their mechanism through structural analysis. To achieve our goal, we incorporate Metal-Organic framework (MOF), with a high aspect ratio, as the nanofiller. We choose MOF due to its flexibility to tune surface chemistry and dimension as well as filler shape. We analyze the effect of two shapes of MOF, one nanosheet (Cu MOF/C2n2d) and the other nanowhisker (Ni MOF/Nnd), on 5 different SPE compositions: EO:Li=14:1, 10:1, 8:1, 6:1, and 3:1 [EO= Ether oxygen, Li= Lithium]. These compositions form 3 types of crystals depending on the lithium-ion content: PEO, PEO6, and PEO3. While PEO6 and PEO3 are conductive polymer-salt co-crystals, PEO is an insulator. In PEO6, two PEO chains wrap around each other to form a cylindrical tunnel-like structure. The lithium ions conduct through the tunnels, while the anions stay outside. In PEO3, the lithium ions and anions form an ion chain, which wraps around PEO. The lithium ions slide along PEO while interacting with the anions. We have achieved significant improvement in crystalline conduction with only 2 wt% Cu MOF loading. We obtain our best conductivity at EO:Li=8:1, where 2 wt% Cu MOF produces greater than 10.
520 $a -5 S/cm conductivity at room temperature. At EO:Li=6:1, the % conductivity increase is between 200-900% in the entire temperature range with 2 wt% Cu MOF, which is a significant achievement for an electrolyte containing high molecular weight PEO6. We have discovered that the shape of the MOF filler and thermal annealing time play very important roles in crystalline conductivity. 2D Cu MOF has higher conductivity than 1D Ni MOF for all the compositions, and 10 days of thermal annealing produces more effective conductive crystals than those produced after a longer annealing time. Conductivity drops significantly after one month as a result of excessive bulk crystallization. For practical battery applications, it would be imperative to control the extent of the crystallinity of the crystalline polymer electrolytes. We recommend crosslinking the composites during initial thermal annealing to hold the effective crystal structures in place. Although we are still quite far away from reaching the target room-temperature conductivity (10.
520 $a -3 S/cm) for commercial battery applications, this study is the first demonstration of MOF-assisted crystalline conduction. In the field of MOF nanofillers, this opens up the opportunity to explore a novel mechanism for improving conductivity, where ion conduction is decoupled from polymer segmental motion. The combined use of crystalline polymer electrolyte and MOF has the potential to limit anion movement and dendrite formation, which paves the way to design a safe and efficient battery.
590 $a School code: 0176.
650 4 $a Polymers. $3 535398
650 4 $a Transmission electron microscopy. $3 567074
650 4 $a Electrolytes. $3 656992
650 4 $a Oxygen. $3 714746
650 4 $a Graphite. $3 651851
650 4 $a Spectrum analysis. $3 520440
650 4 $a Nanoparticles. $3 605747
650 4 $a Cellulose. $3 588995
650 4 $a Aging. $3 543123
650 4 $a Temperature. $3 711968
650 4 $a Conductivity. $3 3681488
650 4 $a Electric fields. $3 880423
650 4 $a Heat. $3 573595
650 4 $a X rays. $3 3682558
650 4 $a Energy storage. $3 652130
650 4 $a Crystals. $3 524190
650 4 $a Lithium. $3 1638490
650 4 $a Annealing. $2 lcstt $3 3267268
650 4 $a Polymer chemistry. $3 3173488
650 4 $a Electrical engineering. $3 649834
650 4 $a Alternative energy. $3 3436775
650 4 $a Chemical engineering. $3 560457
653 $a Lithium ion batteries
653 $a Polymer electrolytes
690 $a 0493
690 $a 0495
690 $a 0544
690 $a 0542
690 $a 0363
710 2 $a The Pennsylvania State University. $3 699896
773 0 $t Dissertations Abstracts International $g 83-03B.
790 $a 0176
791 $a Ph.D.
792 $a 2021
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28841678