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Iron-catalyzed C-H/C-H coupling for ...

Doba, Takahiro.

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Iron-catalyzed C-H/C-H coupling for synthesis of functional small molecules and polymers

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Iron-catalyzed C-H/C-H coupling for synthesis of functional small molecules and polymers/ by Takahiro Doba.
作者:	Doba, Takahiro.
出版者:	Singapore :Springer Nature Singapore : : 2023.,
面頁冊數:	xiv, 153 p. :ill. (some col.), digital ;24 cm.
附註:	"Doctoral thesis accepted by The University of Tokyo, Tokyo, Japan."
內容註:	1. General Introduction -- 2. Iron-Catalyzed Regioselective Thienyl C-H/C-H Homocoupling -- 3. Development of a Synthetic Method for Tridentate Phosphine Ligands -- 4. Iron-Catalyzed Regioselective Thienyl C-H/C-H Polycondensation -- 5. Iron-Catalyzed Oxidative C-H Alkenylation of Thiophenes with Enamines -- 6. Conclusions and Perspectives.
Contained By:	Springer Nature eBook
標題:	Thiophenes - Synthesis. -
電子資源:	https://doi.org/10.1007/978-981-99-4121-6
ISBN:	9789819941216

Iron-catalyzed C-H/C-H coupling for synthesis of functional small molecules and polymers
Doba, Takahiro.

Iron-catalyzed C-H/C-H coupling for synthesis of functional small molecules and polymers[electronic resource] /by Takahiro Doba. - Singapore :Springer Nature Singapore :2023. - xiv, 153 p. :ill. (some col.), digital ;24 cm. - Springer theses,2190-5061. - Springer theses..

"Doctoral thesis accepted by The University of Tokyo, Tokyo, Japan."

1. General Introduction -- 2. Iron-Catalyzed Regioselective Thienyl C-H/C-H Homocoupling -- 3. Development of a Synthetic Method for Tridentate Phosphine Ligands -- 4. Iron-Catalyzed Regioselective Thienyl C-H/C-H Polycondensation -- 5. Iron-Catalyzed Oxidative C-H Alkenylation of Thiophenes with Enamines -- 6. Conclusions and Perspectives.

This thesis describes the development of iron-catalyzed thienyl C-H/C-H coupling. This is applied to the synthesis of highly conjugated and electron-rich thiophene compounds of interest in materials science by utilization of low redox potential of iron in combination with a mild oxalate oxidant. Transition-metal-catalyzed C(sp2)-H/C(sp2)-H coupling has attracted much attention as one of the most straightforward methods to construct C(sp2)-C(sp2) bonds. However, application of this ideal transformation to the synthesis of redox-sensitive pi-materials was hindered by the requirement of a strong oxidant for catalyst turnover. This limitation originates primarily from the large redox potential of conventional transition-metal catalysts such as palladium and rhodium. This thesis shows that the efficiency of C-H activation was significantly improved by introduction of a new conjugated tridentate phosphine ligand, giving direct access to polymeric thiophene materials from simple thiophene monomers. Considering the importance of environmentally friendly organic synthesis in terms of UN Sustainable Development Goals, the reactions described herein highlight the potential of iron, the most abundant transition-metal on earth, for the direct synthesis of functional small molecules and polymers of importance in energy device applications.

ISBN: 9789819941216

Standard No.: 10.1007/978-981-99-4121-6doiSubjects--Topical Terms:

3662770
Thiophenes
--Synthesis.

LC Class. No.: QD505

Dewey Class. No.: 541.395

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520 $a This thesis describes the development of iron-catalyzed thienyl C-H/C-H coupling. This is applied to the synthesis of highly conjugated and electron-rich thiophene compounds of interest in materials science by utilization of low redox potential of iron in combination with a mild oxalate oxidant. Transition-metal-catalyzed C(sp2)-H/C(sp2)-H coupling has attracted much attention as one of the most straightforward methods to construct C(sp2)-C(sp2) bonds. However, application of this ideal transformation to the synthesis of redox-sensitive pi-materials was hindered by the requirement of a strong oxidant for catalyst turnover. This limitation originates primarily from the large redox potential of conventional transition-metal catalysts such as palladium and rhodium. This thesis shows that the efficiency of C-H activation was significantly improved by introduction of a new conjugated tridentate phosphine ligand, giving direct access to polymeric thiophene materials from simple thiophene monomers. Considering the importance of environmentally friendly organic synthesis in terms of UN Sustainable Development Goals, the reactions described herein highlight the potential of iron, the most abundant transition-metal on earth, for the direct synthesis of functional small molecules and polymers of importance in energy device applications.
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