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Investigations of Trace Element Tita...

Osborne, Zachary R.

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Investigations of Trace Element Titanium in Silica Minerals.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Investigations of Trace Element Titanium in Silica Minerals./
Author:	Osborne, Zachary R.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2021,
Description:	140 p.
Notes:	Source: Dissertations Abstracts International, Volume: 83-04, Section: B.
Contained By:	Dissertations Abstracts International83-04B.
Subject:	Geology. -
Online resource:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28720048
ISBN:	9798460465019

Investigations of Trace Element Titanium in Silica Minerals.
Osborne, Zachary R.

Investigations of Trace Element Titanium in Silica Minerals. - Ann Arbor : ProQuest Dissertations & Theses, 2021 - 140 p.

Source: Dissertations Abstracts International, Volume: 83-04, Section: B.

Thesis (Ph.D.)--Syracuse University, 2021.

This item must not be sold to any third party vendors.

Quartz is a common mineral in many igneous, metamorphic, and sedimentary rocks because it is stable over a wide range of pressure (P) and temperature (T) conditions; therefore, quartz is an excellent mineral to target for thermobarometric uses. Thermobarometry is the quantitative determination of the pressure (baro-) and temperature (thermo-) conditions at which a natural rock sample reached chemical equilibrium. This dissertation contains three chapters describing mineral synthesis experiments that quantify and define the trace-element solubility behavior of titanium (Ti) in the silica minerals quartz and coesite, to advance the understanding and application of trace-element thermobarometry.Chapter 1 details the experiments that were conducted to quantify the pressure and temperature effects of Ti-in-coesite (TitaniC) solubility to develop the first Ti-in-coesite thermobarometer. The Ti-in-coesite thermobarometer was applied to coesite samples from two UHP (ultra high-pressure) metamorphic locales, the western Alps, Italy, (Dora-Maira) and Papua New Guinea; the estimates for each respective sample were in excellent agreement with previously reported P-T conditions. Chapter 2 involves experiments which Ti solubility in quartz was investigated at previously unexplored conditions, focused on extending and improving the Ti-in-quartz (TitaniQ) solubility model (Thomas et al. 2010). Additional data enabled characterization of Ti-in-quartz solubility across much of the α- and β-quartz stability fields and demonstrated that Ti concentrations in β-quartz decrease linearly with increasing pressure, while Ti-in-quartz concentrations in α-quartz decrease nonlinearly with increasing pressure at the conditions studied. New thermobarometric model equations for Ti solubility in α-quartz, β-quartz, and α-β quartz combined were developed; remarkable agreement between calculated and measured experimental P−T conditions using the Zr-in-rutile and Ti-in-quartz solubility models demonstrated that the solubility models accurately describe the equilibrium solubility of titanium in quartz. Chapter 3 describes experiments that synthesized quartz in the presence of titanite at sub-unity titania activity (αTiO2) conditions. Ti-in-quartz concentrations and known experiment P-T conditions were entered into the TitaniQ solubility models to estimate αTiO2 values for the experimental system. The estimated αTiO2 values were in excellent agreement with those calculated by using the mineral reactions and thermodynamic parameters from internally consistent datasets (Berman 1988; Holland and Powell 2011); this provides another source of validation of the Ti-in-quartz solubility models (Thomas et al. 2010; Osborne et al. 2021).

ISBN: 9798460465019Subjects--Topical Terms:

516570
Geology.
Subjects--Index Terms:

Coesite

Investigations of Trace Element Titanium in Silica Minerals.
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245 1 0 $a Investigations of Trace Element Titanium in Silica Minerals.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2021
300 $a 140 p.
500 $a Source: Dissertations Abstracts International, Volume: 83-04, Section: B.
500 $a Advisor: Thomas, Jay.
502 $a Thesis (Ph.D.)--Syracuse University, 2021.
506 $a This item must not be sold to any third party vendors.
520 $a Quartz is a common mineral in many igneous, metamorphic, and sedimentary rocks because it is stable over a wide range of pressure (P) and temperature (T) conditions; therefore, quartz is an excellent mineral to target for thermobarometric uses. Thermobarometry is the quantitative determination of the pressure (baro-) and temperature (thermo-) conditions at which a natural rock sample reached chemical equilibrium. This dissertation contains three chapters describing mineral synthesis experiments that quantify and define the trace-element solubility behavior of titanium (Ti) in the silica minerals quartz and coesite, to advance the understanding and application of trace-element thermobarometry.Chapter 1 details the experiments that were conducted to quantify the pressure and temperature effects of Ti-in-coesite (TitaniC) solubility to develop the first Ti-in-coesite thermobarometer. The Ti-in-coesite thermobarometer was applied to coesite samples from two UHP (ultra high-pressure) metamorphic locales, the western Alps, Italy, (Dora-Maira) and Papua New Guinea; the estimates for each respective sample were in excellent agreement with previously reported P-T conditions. Chapter 2 involves experiments which Ti solubility in quartz was investigated at previously unexplored conditions, focused on extending and improving the Ti-in-quartz (TitaniQ) solubility model (Thomas et al. 2010). Additional data enabled characterization of Ti-in-quartz solubility across much of the α- and β-quartz stability fields and demonstrated that Ti concentrations in β-quartz decrease linearly with increasing pressure, while Ti-in-quartz concentrations in α-quartz decrease nonlinearly with increasing pressure at the conditions studied. New thermobarometric model equations for Ti solubility in α-quartz, β-quartz, and α-β quartz combined were developed; remarkable agreement between calculated and measured experimental P−T conditions using the Zr-in-rutile and Ti-in-quartz solubility models demonstrated that the solubility models accurately describe the equilibrium solubility of titanium in quartz. Chapter 3 describes experiments that synthesized quartz in the presence of titanite at sub-unity titania activity (αTiO2) conditions. Ti-in-quartz concentrations and known experiment P-T conditions were entered into the TitaniQ solubility models to estimate αTiO2 values for the experimental system. The estimated αTiO2 values were in excellent agreement with those calculated by using the mineral reactions and thermodynamic parameters from internally consistent datasets (Berman 1988; Holland and Powell 2011); this provides another source of validation of the Ti-in-quartz solubility models (Thomas et al. 2010; Osborne et al. 2021).
590 $a School code: 0659.
650 4 $a Geology. $3 516570
650 4 $a Mineralogy. $3 516743
653 $a Coesite
653 $a Quartz
653 $a Thermobarometry
653 $a Ti-in-coesite
653 $a Ti-in-quartz
653 $a Zr-in-rutile
690 $a 0372
690 $a 0411
710 2 $a Syracuse University. $b Earth Sciences. $3 3265748
773 0 $t Dissertations Abstracts International $g 83-04B.
790 $a 0659
791 $a Ph.D.
792 $a 2021
793 $a English
856 4 0 $u https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28720048