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Renewable Feedstocks Towards a Susta...

Sajjad, Hussnain.

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Renewable Feedstocks Towards a Sustainable Future for Polymers.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Renewable Feedstocks Towards a Sustainable Future for Polymers./
Author:	Sajjad, Hussnain.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2021,
Description:	207 p.
Notes:	Source: Dissertations Abstracts International, Volume: 82-10, Section: B.
Contained By:	Dissertations Abstracts International82-10B.
Subject:	Thermodynamics. -
Online resource:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28320161
ISBN:	9798728229100

Renewable Feedstocks Towards a Sustainable Future for Polymers.
Sajjad, Hussnain.

Renewable Feedstocks Towards a Sustainable Future for Polymers. - Ann Arbor : ProQuest Dissertations & Theses, 2021 - 207 p.

Source: Dissertations Abstracts International, Volume: 82-10, Section: B.

Thesis (Ph.D.)--University of Minnesota, 2021.

This item must not be sold to any third party vendors.

Biomass has tremendous potential to serve as a sustainable replacement for the limited resources we currently exploit to manufacture polymeric materials. Identifying and testing novel, renewable feedstocks for polymer synthesis is a grand challenge which the topic of this thesis aims to address. The first area of research focuses on utilizing fatty acid derivatives and bio-derivable triacetic acid lactone to produce new acrylic triblock copolymers for pressure-sensitive adhesives. The findings reveal that it is possible to utilize renewable, long-chained alkyl-acrylates with high Me to create useful elastomers. The second area of reach explores the ring opening polymerizations of di-substituted valerolactones derived from triacetic acid lactone. The findings provide valuable insights towards the thermodynamics and kinetics of polymerization of substituted valerolactones. Finally, the third area of research details the synthesis of novel anhydride-like monomers obtained from bio-derived itaconic acid. The monomers were polymerized via photoinitiated thiol-ene chemistry to obtain thermosets that were found to be degradable in aqueous environments.

ISBN: 9798728229100Subjects--Topical Terms:

517304
Thermodynamics.
Subjects--Index Terms:

Renewable feedstocks

Renewable Feedstocks Towards a Sustainable Future for Polymers.
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260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2021
300 $a 207 p.
500 $a Source: Dissertations Abstracts International, Volume: 82-10, Section: B.
500 $a Advisor: Reineke, Theresa M.;Tolman, William B.
502 $a Thesis (Ph.D.)--University of Minnesota, 2021.
506 $a This item must not be sold to any third party vendors.
520 $a Biomass has tremendous potential to serve as a sustainable replacement for the limited resources we currently exploit to manufacture polymeric materials. Identifying and testing novel, renewable feedstocks for polymer synthesis is a grand challenge which the topic of this thesis aims to address. The first area of research focuses on utilizing fatty acid derivatives and bio-derivable triacetic acid lactone to produce new acrylic triblock copolymers for pressure-sensitive adhesives. The findings reveal that it is possible to utilize renewable, long-chained alkyl-acrylates with high Me to create useful elastomers. The second area of reach explores the ring opening polymerizations of di-substituted valerolactones derived from triacetic acid lactone. The findings provide valuable insights towards the thermodynamics and kinetics of polymerization of substituted valerolactones. Finally, the third area of research details the synthesis of novel anhydride-like monomers obtained from bio-derived itaconic acid. The monomers were polymerized via photoinitiated thiol-ene chemistry to obtain thermosets that were found to be degradable in aqueous environments.
590 $a School code: 0130.
650 4 $a Thermodynamics. $3 517304
650 4 $a Polymer chemistry. $3 3173488
650 4 $a Sustainability. $3 1029978
653 $a Renewable feedstocks
653 $a Fatty acids
653 $a Triacetic acid lactone
653 $a Triblock copolymers
653 $a Polymer manufacturing
653 $a Valerolactones
690 $a 0640
690 $a 0348
690 $a 0495
710 2 $a University of Minnesota. $b Chemistry. $3 1265998
773 0 $t Dissertations Abstracts International $g 82-10B.
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