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Catalytic Utilization of Carbon Diox...

Jawad, Abbas Alaa.

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Catalytic Utilization of Carbon Dioxide as Renewable Feedstock for Production of Chemicals and Fuels.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Catalytic Utilization of Carbon Dioxide as Renewable Feedstock for Production of Chemicals and Fuels./
Author:	Jawad, Abbas Alaa.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2020,
Description:	201 p.
Notes:	Source: Dissertations Abstracts International, Volume: 82-08, Section: B.
Contained By:	Dissertations Abstracts International82-08B.
Subject:	Chemical engineering. -
Online resource:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28157164
ISBN:	9798569976423

Catalytic Utilization of Carbon Dioxide as Renewable Feedstock for Production of Chemicals and Fuels.
Jawad, Abbas Alaa.

Catalytic Utilization of Carbon Dioxide as Renewable Feedstock for Production of Chemicals and Fuels. - Ann Arbor : ProQuest Dissertations & Theses, 2020 - 201 p.

Source: Dissertations Abstracts International, Volume: 82-08, Section: B.

Thesis (Ph.D.)--Missouri University of Science and Technology, 2020.

This item must not be sold to any third party vendors.

The utilization of CO2 as a renewable feedstock for producing commodity chemicals and fuels is an interesting challenge to explore new concepts and opportunities in catalysis and industrial chemistry. This sustainable approach not only leads to production of useful chemicals, but also has the potential to mitigate anthropogenic CO2 emissions to the atmosphere. CO2 itself is a sustainable and inexhaustibly available carbon source, however, it is inextricably linked to its inherent inertness. It is a thermodynamically stable molecule (ΔGf = -394.01 kJ.mol−1) with high oxidation state, hence, reactions of CO2 must be combined with a high-energy reactant to gain a thermodynamic driving force. It has been shown that catalytic reaction is the best strategy to address this challenge. Although several processes for production of urea, methanol, and salicylic acid have been developed through CO2 utilization, many of them rely on extremes of temperature and pressure to work. Owing to the growing energy demand and increasing atmospheric carbon dioxide (CO2) concentration, it is desirable to identify effective hydrocarbon transformation reactions in tandem with CO2 conversion. Research on direct transformation of light paraffins -such as methane, ethane and propane into light olefins -such as ethylene and propylene and aromatics has gained considerable importance recently because of its potential large-scale implementation for production of fine chemicals, pharmaceuticals, plastics and liquid fuels from C1-C4 hydrocarbons in the shale gas. The catalytic conversion of propane into propylene in the presence of CO2 as a soft oxidant opens opportunities to simultaneously reduce CO2 to CO and convert paraffin into value-added products.

ISBN: 9798569976423Subjects--Topical Terms:

560457
Chemical engineering.
Subjects--Index Terms:

Renewable feedstock

Catalytic Utilization of Carbon Dioxide as Renewable Feedstock for Production of Chemicals and Fuels.
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245 1 0 $a Catalytic Utilization of Carbon Dioxide as Renewable Feedstock for Production of Chemicals and Fuels.
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300 $a 201 p.
500 $a Source: Dissertations Abstracts International, Volume: 82-08, Section: B.
500 $a Advisor: Rownaghi, Ali.
502 $a Thesis (Ph.D.)--Missouri University of Science and Technology, 2020.
506 $a This item must not be sold to any third party vendors.
520 $a The utilization of CO2 as a renewable feedstock for producing commodity chemicals and fuels is an interesting challenge to explore new concepts and opportunities in catalysis and industrial chemistry. This sustainable approach not only leads to production of useful chemicals, but also has the potential to mitigate anthropogenic CO2 emissions to the atmosphere. CO2 itself is a sustainable and inexhaustibly available carbon source, however, it is inextricably linked to its inherent inertness. It is a thermodynamically stable molecule (ΔGf = -394.01 kJ.mol−1) with high oxidation state, hence, reactions of CO2 must be combined with a high-energy reactant to gain a thermodynamic driving force. It has been shown that catalytic reaction is the best strategy to address this challenge. Although several processes for production of urea, methanol, and salicylic acid have been developed through CO2 utilization, many of them rely on extremes of temperature and pressure to work. Owing to the growing energy demand and increasing atmospheric carbon dioxide (CO2) concentration, it is desirable to identify effective hydrocarbon transformation reactions in tandem with CO2 conversion. Research on direct transformation of light paraffins -such as methane, ethane and propane into light olefins -such as ethylene and propylene and aromatics has gained considerable importance recently because of its potential large-scale implementation for production of fine chemicals, pharmaceuticals, plastics and liquid fuels from C1-C4 hydrocarbons in the shale gas. The catalytic conversion of propane into propylene in the presence of CO2 as a soft oxidant opens opportunities to simultaneously reduce CO2 to CO and convert paraffin into value-added products.
590 $a School code: 0587.
650 4 $a Chemical engineering. $3 560457
650 4 $a Industrial engineering. $3 526216
650 4 $a Hydrologic sciences. $3 3168407
650 4 $a Materials science. $3 543314
650 4 $a Thermodynamics. $3 517304
650 4 $a Atmospheric sciences. $3 3168354
650 4 $a Sustainability. $3 1029978
653 $a Renewable feedstock
653 $a Commodity chemicals
653 $a Commodity fuels
653 $a Industrial chemistry
653 $a CO2 emissions
653 $a Available carbon source
653 $a Hydrocarbon storage
653 $a Ethylene
653 $a Propylene
690 $a 0542
690 $a 0474
690 $a 0794
690 $a 0640
690 $a 0388
690 $a 0546
690 $a 0348
690 $a 0725
710 2 $a Missouri University of Science and Technology. $b Chemical Engineering. $3 2104033
773 0 $t Dissertations Abstracts International $g 82-08B.
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791 $a Ph.D.
792 $a 2020
793 $a English
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