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Exploring Main Group Phosphorus Chem...

Szkop, Kevin Martin.

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Exploring Main Group Phosphorus Chemistry: Lewis Acid Catalysis and Applications of Low-Coordinate Building Blocks.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Exploring Main Group Phosphorus Chemistry: Lewis Acid Catalysis and Applications of Low-Coordinate Building Blocks./
Author:	Szkop, Kevin Martin.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2020,
Description:	339 p.
Notes:	Source: Dissertations Abstracts International, Volume: 82-06, Section: B.
Contained By:	Dissertations Abstracts International82-06B.
Subject:	Chemistry. -
Online resource:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=27837850
ISBN:	9798698544067

Exploring Main Group Phosphorus Chemistry: Lewis Acid Catalysis and Applications of Low-Coordinate Building Blocks.
Szkop, Kevin Martin.

Exploring Main Group Phosphorus Chemistry: Lewis Acid Catalysis and Applications of Low-Coordinate Building Blocks. - Ann Arbor : ProQuest Dissertations & Theses, 2020 - 339 p.

Source: Dissertations Abstracts International, Volume: 82-06, Section: B.

Thesis (Ph.D.)--University of Toronto (Canada), 2020.

This item must not be sold to any third party vendors.

The study of main-group elements in unique coordination environments is of fundamental interest and serves to deepen our understanding of bonding and chemical trends. In recent years, interest in phosphorus chemistry pertaining to catalysis and synthesis has experienced a resurgence. Herein, contributions towards expanding the fields of phosphorus Lewis acid catalysis and the construction of simple phosphorus-containing organic molecules are delineated. Phosphonium polycationic Lewis acid catalysts of increasing stability towards air and moisture were synthesized and shown to mediate a range of organic transformations. The chemistry of the 2-phosphaethynolate anion ([PCO]-), which has generated a flurry of activity in recent years, has been studied in the context of electrophilic boranes. The phosphaketene Ph3GePCO, derived from [PCO]-, has been employed in the formation of formylphosphines, diphosphaureas, and substituted phosphaalkenes. Dibenzo-7-phosphanorbornadienes were used to access the acyl(chloro)phosphine functional group.

ISBN: 9798698544067Subjects--Topical Terms:

516420
Chemistry.
Subjects--Index Terms:

Phosphorus Lewis acid catalysis

Exploring Main Group Phosphorus Chemistry: Lewis Acid Catalysis and Applications of Low-Coordinate Building Blocks.
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500 $a Source: Dissertations Abstracts International, Volume: 82-06, Section: B.
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520 $a The study of main-group elements in unique coordination environments is of fundamental interest and serves to deepen our understanding of bonding and chemical trends. In recent years, interest in phosphorus chemistry pertaining to catalysis and synthesis has experienced a resurgence. Herein, contributions towards expanding the fields of phosphorus Lewis acid catalysis and the construction of simple phosphorus-containing organic molecules are delineated. Phosphonium polycationic Lewis acid catalysts of increasing stability towards air and moisture were synthesized and shown to mediate a range of organic transformations. The chemistry of the 2-phosphaethynolate anion ([PCO]-), which has generated a flurry of activity in recent years, has been studied in the context of electrophilic boranes. The phosphaketene Ph3GePCO, derived from [PCO]-, has been employed in the formation of formylphosphines, diphosphaureas, and substituted phosphaalkenes. Dibenzo-7-phosphanorbornadienes were used to access the acyl(chloro)phosphine functional group.
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