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Improving Gas Barrier Properties of ...

Natarajan, Madhumitha.

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Improving Gas Barrier Properties of Sugarcane-Based LLDPE with Cellulose Nanocrystals.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Improving Gas Barrier Properties of Sugarcane-Based LLDPE with Cellulose Nanocrystals./
Author:	Natarajan, Madhumitha.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2021,
Description:	105 p.
Notes:	Source: Masters Abstracts International, Volume: 82-10.
Contained By:	Masters Abstracts International82-10.
Subject:	Materials science. -
Online resource:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28415296
ISBN:	9798708748461

Improving Gas Barrier Properties of Sugarcane-Based LLDPE with Cellulose Nanocrystals.
Natarajan, Madhumitha.

Improving Gas Barrier Properties of Sugarcane-Based LLDPE with Cellulose Nanocrystals. - Ann Arbor : ProQuest Dissertations & Theses, 2021 - 105 p.

Source: Masters Abstracts International, Volume: 82-10.

Thesis (M.S.)--Michigan State University, 2021.

This item must not be sold to any third party vendors.

This study was aimed at improving the gas barrier property of sugarcane-based LLDPE using cellulose nanocrystals (CNCs). Specifically, this study evaluated the effect of testing methods (isostatic versus gravimetric) on CO2 permeability coefficient (PCO2) and/or O2 permeability coefficient (PO2) of various bio-PE grades with different densities (LLDPE, LDPE, and HDPE) as well as the effect of CNC content on crystallinity, tortuosity factor, and gas barrier properties of bio-LLDPE sheets and films. The isostatic and gravimetric methods yielded similar PCO2, irrespective of PE grade. However, the PCO2 negatively correlated with PE density. All nanocomposites showed considerable improvement in gas barrier irrespective of the CNC content. The PCO2 of LLDPE sheets decreased by 36% by adding 10 wt.% of CNCs into the sheet. Similarly, a significant decline in both PO2 (about 50%) and PCO2 (about 33%) of LLDPE films was obtained by adding 2.5 wt.% of CNCs into the films. Nevertheless, no correlation was established between gas permeability and percent crystallinity of LLDPE sheet since the PCO2 decreased almost linearly with increasing CNC content whereas the percent crystallinity of LLDPE increased only up to 2.5% CNC content and remained constant thereafter. In contrast, the tortuosity factors calculated from the diffusion coefficients increased almost linearly with CNC contents and correlated well with the gas permeability improvement in the bio-LLDPE-based nanocomposites. Consequently, the enhanced gas barrier in the nanocomposite was assigned to the tortuosity effect created by the impermeable cellulose nanocrystals rather than the changes in percent crystallinity.

ISBN: 9798708748461Subjects--Topical Terms:

543314
Materials science.
Subjects--Index Terms:

Bio-polyethylenes

Improving Gas Barrier Properties of Sugarcane-Based LLDPE with Cellulose Nanocrystals.
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300 $a 105 p.
500 $a Source: Masters Abstracts International, Volume: 82-10.
500 $a Advisor: Matuana, Laurent.
502 $a Thesis (M.S.)--Michigan State University, 2021.
506 $a This item must not be sold to any third party vendors.
520 $a This study was aimed at improving the gas barrier property of sugarcane-based LLDPE using cellulose nanocrystals (CNCs). Specifically, this study evaluated the effect of testing methods (isostatic versus gravimetric) on CO2 permeability coefficient (PCO2) and/or O2 permeability coefficient (PO2) of various bio-PE grades with different densities (LLDPE, LDPE, and HDPE) as well as the effect of CNC content on crystallinity, tortuosity factor, and gas barrier properties of bio-LLDPE sheets and films. The isostatic and gravimetric methods yielded similar PCO2, irrespective of PE grade. However, the PCO2 negatively correlated with PE density. All nanocomposites showed considerable improvement in gas barrier irrespective of the CNC content. The PCO2 of LLDPE sheets decreased by 36% by adding 10 wt.% of CNCs into the sheet. Similarly, a significant decline in both PO2 (about 50%) and PCO2 (about 33%) of LLDPE films was obtained by adding 2.5 wt.% of CNCs into the films. Nevertheless, no correlation was established between gas permeability and percent crystallinity of LLDPE sheet since the PCO2 decreased almost linearly with increasing CNC content whereas the percent crystallinity of LLDPE increased only up to 2.5% CNC content and remained constant thereafter. In contrast, the tortuosity factors calculated from the diffusion coefficients increased almost linearly with CNC contents and correlated well with the gas permeability improvement in the bio-LLDPE-based nanocomposites. Consequently, the enhanced gas barrier in the nanocomposite was assigned to the tortuosity effect created by the impermeable cellulose nanocrystals rather than the changes in percent crystallinity.
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