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Process Intensification of Fuel Synt...
~
Hartvigsen, Jeremy Lee.
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Process Intensification of Fuel Synthesis and Electrolysis.
Record Type:
Electronic resources : Monograph/item
Title/Author:
Process Intensification of Fuel Synthesis and Electrolysis./
Author:
Hartvigsen, Jeremy Lee.
Published:
Ann Arbor : ProQuest Dissertations & Theses, : 2020,
Description:
119 p.
Notes:
Source: Dissertations Abstracts International, Volume: 82-08, Section: B.
Contained By:
Dissertations Abstracts International82-08B.
Subject:
Alternative energy. -
Online resource:
https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28257228
ISBN:
9798569966929
Process Intensification of Fuel Synthesis and Electrolysis.
Hartvigsen, Jeremy Lee.
Process Intensification of Fuel Synthesis and Electrolysis.
- Ann Arbor : ProQuest Dissertations & Theses, 2020 - 119 p.
Source: Dissertations Abstracts International, Volume: 82-08, Section: B.
Thesis (Ph.D.)--Missouri University of Science and Technology, 2020.
This item must not be sold to any third party vendors.
As more renewable energy is added to the electric grid, energy storage becomes a high priority. Suggestions have been made for energy storage in the form of fuel and chemicals. Currently, Solid Oxide Electrolysis systems can operate in endothermic mode and reduce the electrical requirement by supplying heat. Fuel synthesis from syngas is exothermic and can supply heat. However, the temperature mismatch in the normal operation of the electrolysis step and fuel synthesis step makes the direct utilization of this heat impossible. This work explores possibilities of alternate arrangements of coupling electrochemical systems and chemical synthesis. This work also explores potential for heat integration between the electrolysis and synthesis steps. This is done through exploring higher temperature fuel synthesis systems, and a new intermediate temperature electrolysis system.The successful use of a Mo2C/HZSM-5 catalyst for ethylene production is shown. Analysis of potential benefits and limitations of each technological approach are examined. The breakeven carbon pricing for the hybrid energy system production of chemicals to be competitive with fossil-fuel based chemical production is calculated.
ISBN: 9798569966929Subjects--Topical Terms:
3436775
Alternative energy.
Subjects--Index Terms:
Hydrogen
Process Intensification of Fuel Synthesis and Electrolysis.
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As more renewable energy is added to the electric grid, energy storage becomes a high priority. Suggestions have been made for energy storage in the form of fuel and chemicals. Currently, Solid Oxide Electrolysis systems can operate in endothermic mode and reduce the electrical requirement by supplying heat. Fuel synthesis from syngas is exothermic and can supply heat. However, the temperature mismatch in the normal operation of the electrolysis step and fuel synthesis step makes the direct utilization of this heat impossible. This work explores possibilities of alternate arrangements of coupling electrochemical systems and chemical synthesis. This work also explores potential for heat integration between the electrolysis and synthesis steps. This is done through exploring higher temperature fuel synthesis systems, and a new intermediate temperature electrolysis system.The successful use of a Mo2C/HZSM-5 catalyst for ethylene production is shown. Analysis of potential benefits and limitations of each technological approach are examined. The breakeven carbon pricing for the hybrid energy system production of chemicals to be competitive with fossil-fuel based chemical production is calculated.
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https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28257228
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