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Photochemistry of Polycyclic Aromati...

Haynes, John P.

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Photochemistry of Polycyclic Aromatic Hydrocarbons with Environmentally Relevant Metals.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Photochemistry of Polycyclic Aromatic Hydrocarbons with Environmentally Relevant Metals./
Author:	Haynes, John P.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2018,
Description:	125 p.
Notes:	Source: Dissertations Abstracts International, Volume: 80-02, Section: B.
Contained By:	Dissertations Abstracts International80-02B.
Subject:	Atmospheric Chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10825233
ISBN:	9780438205642

Photochemistry of Polycyclic Aromatic Hydrocarbons with Environmentally Relevant Metals.
Haynes, John P.

Photochemistry of Polycyclic Aromatic Hydrocarbons with Environmentally Relevant Metals. - Ann Arbor : ProQuest Dissertations & Theses, 2018 - 125 p.

Source: Dissertations Abstracts International, Volume: 80-02, Section: B.

Thesis (Ph.D.)--University of Denver, 2018.

This item must not be sold to any third party vendors.

The details of the work presented in this dissertation focus on simulated reactions in the atmosphere and water systems between persistent aromatic compounds and varying species of metals with an emphasis on iron. Bulk water suspensions of a standard soil and polycyclic aromatic hydrocarbons (PAH) were analyzed for soluble iron by inductively-coupled plasma mass spectroscopy (ICP-MS) following a 16 hour reaction period using simulated sunlight. Significant increases in soluble iron were only seen with 2-3 ring linear PAH and carboxylic acids. A two-stage study was conducted to investigate the potential for and possible mechanisms involving the photo-oxidation of PAH into humic-like substances (HULIS). Aqueous suspensions of PAH and oxidized PAH products are illuminated by a bench solar simulator and resulting samples are analyzed by high-pressure liquid chromatography (HPLC), UV-Vis, attenuated total reflectance Fourier transformer infrared spectroscopy (ATR-FTIR), solid-phase extraction (SPE), and electrospray ionization/atmospheric pressure chemical ionization mass spectroscopy (ESI/APCI-MS). HULIS production is based on comparison to SRFA and is observed in short chain PAH following a surface dependent path through naphthalene derivative intermediate structures. These results help explain brown carbon and health effects observed in areas affected by urban emissions.

ISBN: 9780438205642Subjects--Topical Terms:

1669583
Atmospheric Chemistry.
Subjects--Index Terms:

Atmospheric processing

Photochemistry of Polycyclic Aromatic Hydrocarbons with Environmentally Relevant Metals.
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100 1 $a Haynes, John P. $3 3549664
245 1 0 $a Photochemistry of Polycyclic Aromatic Hydrocarbons with Environmentally Relevant Metals.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2018
300 $a 125 p.
500 $a Source: Dissertations Abstracts International, Volume: 80-02, Section: B.
500 $a Publisher info.: Dissertation/Thesis.
500 $a Advisor: Majestic, Brian J.;Murphy, Shannon M.
502 $a Thesis (Ph.D.)--University of Denver, 2018.
506 $a This item must not be sold to any third party vendors.
520 $a The details of the work presented in this dissertation focus on simulated reactions in the atmosphere and water systems between persistent aromatic compounds and varying species of metals with an emphasis on iron. Bulk water suspensions of a standard soil and polycyclic aromatic hydrocarbons (PAH) were analyzed for soluble iron by inductively-coupled plasma mass spectroscopy (ICP-MS) following a 16 hour reaction period using simulated sunlight. Significant increases in soluble iron were only seen with 2-3 ring linear PAH and carboxylic acids. A two-stage study was conducted to investigate the potential for and possible mechanisms involving the photo-oxidation of PAH into humic-like substances (HULIS). Aqueous suspensions of PAH and oxidized PAH products are illuminated by a bench solar simulator and resulting samples are analyzed by high-pressure liquid chromatography (HPLC), UV-Vis, attenuated total reflectance Fourier transformer infrared spectroscopy (ATR-FTIR), solid-phase extraction (SPE), and electrospray ionization/atmospheric pressure chemical ionization mass spectroscopy (ESI/APCI-MS). HULIS production is based on comparison to SRFA and is observed in short chain PAH following a surface dependent path through naphthalene derivative intermediate structures. These results help explain brown carbon and health effects observed in areas affected by urban emissions.
590 $a School code: 0061.
650 4 $a Atmospheric Chemistry. $3 1669583
650 4 $a Analytical chemistry. $3 3168300
653 $a Atmospheric processing
653 $a Humic-like substances
653 $a Photochemistry
653 $a Polycyclic aromatic hydrocarbons
653 $a Soluble iron
690 $a 0371
690 $a 0486
710 2 $a University of Denver. $b Chemistry and Biochemistry. $3 3546673
773 0 $t Dissertations Abstracts International $g 80-02B.
790 $a 0061
791 $a Ph.D.
792 $a 2018
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10825233