東華大學圖書館 |

Language: English

Help

回圖書館首頁

手機版館藏查詢

Back

Switch To: Labeled | MARC Mode | ISBD

Synthesis of Acetylenic Carbon Molec...

Fujikado, Nancy Matsu.

Linked to FindBook

Google Book

Amazon

博客來

Synthesis of Acetylenic Carbon Molecules via Pulsed Laser Ablation in Ethanol.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Synthesis of Acetylenic Carbon Molecules via Pulsed Laser Ablation in Ethanol./
Author:	Fujikado, Nancy Matsu.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2018,
Description:	101 p.
Notes:	Source: Masters Abstracts International, Volume: 79-11.
Contained By:	Masters Abstracts International79-11.
Subject:	Molecular chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10811117
ISBN:	9780355958478

Synthesis of Acetylenic Carbon Molecules via Pulsed Laser Ablation in Ethanol.
Fujikado, Nancy Matsu.

Synthesis of Acetylenic Carbon Molecules via Pulsed Laser Ablation in Ethanol. - Ann Arbor : ProQuest Dissertations & Theses, 2018 - 101 p.

Source: Masters Abstracts International, Volume: 79-11.

Thesis (M.S.)--Arizona State University, 2018.

This item must not be sold to any third party vendors.

New forms of carbon are being discovered at a rapid rate and prove to be on the frontier of cutting edge technology. Carbon possesses three energetically competitive forms of orbital hybridization, leading to exceptional blends of properties unseen in other materials. Fascinating properties found among carbon allotropes, such as, fullerenes, carbon nanotubes, and graphene have led to new and exciting advancement, with recent applications in defense, energy storage, construction, and electronics. Various combinations of extreme strength, high electrical and thermal conductivity, flexibility, and light weight have led to new durable and flexible display screens, optoelectronics, quantum computing, and strength enhancer coating. The quest for new carbon allotropes and future application persists. Despite the advances in carbon-based technology, researchers have been limited to sp3 and sp2 hybridizations. While sp3 and sp2 hybridizations of carbon are well established and understood, the simplest sp1 hybridized carbon allotrope, carbyne, has been impossible to synthesize and remains elusive. This dissertation presents recent results in characterizing a new sp1 carbon material produced from using pulsed laser ablation in liquid (PLAL) to ablate a gold surface that is immersed in a carbon rich liquid. The PLAL technique provides access to extremely non-thermal environmental conditions where unexplored chemical reactions occur and can be explored to access the production of new materials. A combination of experimental and theoretical results suggests gold clusters can act as stabilizing agents as they react and adsorb onto the surface of one dimensional carbon chains to form a new class of materials termed "pseudocarbynes". Data from several characterization techniques, including Raman spectroscopy, UV/VIS spectroscopy, and transmission electron microscopy (TEM), provide evidence for the existence of pseudocarbyne. This completely new material may possess outstanding properties, a trend seen among carbon allotropes, that can further scientific advancements.

ISBN: 9780355958478Subjects--Topical Terms:

1071612
Molecular chemistry.
Subjects--Index Terms:

Ablation

Synthesis of Acetylenic Carbon Molecules via Pulsed Laser Ablation in Ethanol.
LDR:03394nmm a2200421 4500 001 2272007
005 20201102111645.5
008 220629s2018 ||||||||||||||||| ||eng d
020 $a 9780355958478
035 $a (MiAaPQ)AAI10811117
035 $a (MiAaPQ)asu:18022
035 $a AAI10811117
040 $a MiAaPQ $c MiAaPQ
100 1 $a Fujikado, Nancy Matsu. $3 3549431
245 1 0 $a Synthesis of Acetylenic Carbon Molecules via Pulsed Laser Ablation in Ethanol.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2018
300 $a 101 p.
500 $a Source: Masters Abstracts International, Volume: 79-11.
500 $a Publisher info.: Dissertation/Thesis.
500 $a Advisor: Sayres, Scott G.;Rege, Kaushal.
502 $a Thesis (M.S.)--Arizona State University, 2018.
506 $a This item must not be sold to any third party vendors.
506 $a This item is not available from ProQuest Dissertations & Theses.
520 $a New forms of carbon are being discovered at a rapid rate and prove to be on the frontier of cutting edge technology. Carbon possesses three energetically competitive forms of orbital hybridization, leading to exceptional blends of properties unseen in other materials. Fascinating properties found among carbon allotropes, such as, fullerenes, carbon nanotubes, and graphene have led to new and exciting advancement, with recent applications in defense, energy storage, construction, and electronics. Various combinations of extreme strength, high electrical and thermal conductivity, flexibility, and light weight have led to new durable and flexible display screens, optoelectronics, quantum computing, and strength enhancer coating. The quest for new carbon allotropes and future application persists. Despite the advances in carbon-based technology, researchers have been limited to sp3 and sp2 hybridizations. While sp3 and sp2 hybridizations of carbon are well established and understood, the simplest sp1 hybridized carbon allotrope, carbyne, has been impossible to synthesize and remains elusive. This dissertation presents recent results in characterizing a new sp1 carbon material produced from using pulsed laser ablation in liquid (PLAL) to ablate a gold surface that is immersed in a carbon rich liquid. The PLAL technique provides access to extremely non-thermal environmental conditions where unexplored chemical reactions occur and can be explored to access the production of new materials. A combination of experimental and theoretical results suggests gold clusters can act as stabilizing agents as they react and adsorb onto the surface of one dimensional carbon chains to form a new class of materials termed "pseudocarbynes". Data from several characterization techniques, including Raman spectroscopy, UV/VIS spectroscopy, and transmission electron microscopy (TEM), provide evidence for the existence of pseudocarbyne. This completely new material may possess outstanding properties, a trend seen among carbon allotropes, that can further scientific advancements.
590 $a School code: 0010.
650 4 $a Molecular chemistry. $3 1071612
650 4 $a Physical chemistry. $3 1981412
650 4 $a Nanoscience. $3 587832
653 $a Ablation
653 $a Allotrope
653 $a Carbon
653 $a Gold
653 $a Laser
653 $a Nanoparticle
690 $a 0431
690 $a 0494
690 $a 0565
710 2 $a Arizona State University. $b Chemical Engineering. $3 1682515
773 0 $t Masters Abstracts International $g 79-11.
790 $a 0010
791 $a M.S.
792 $a 2018
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10811117