東華大學圖書館 |

語系: 繁體中文

說明(常見問題)

回圖書館首頁

手機版館藏查詢

登入

回首頁

切換: 標籤 | MARC模式 | ISBD

Synthesis, characterization and reac...

Ghana, Priyabrata.

FindBook

Google Book

Amazon

博客來

Synthesis, characterization and reactivity of Ylidyne and μ-Ylido complexes supported by scorpionato ligands

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Synthesis, characterization and reactivity of Ylidyne and μ-Ylido complexes supported by scorpionato ligands/ by Priyabrata Ghana.
作者:	Ghana, Priyabrata.
出版者:	Cham :Springer International Publishing : : 2019.,
面頁冊數:	xxii, 344 p. :ill. (some col.), digital ;24 cm.
內容註:	Introduction -- Closed shell heavier tetrylidyne complexes of group 6 metals -- Open-shell heavier tetrylidyne complexes of group 6 transition metals -- Germylidyne mediated C-C coupling reaction of isonitriles - formation of an N-heterocyclic germylene -- A new method for the synthesis of manganese tetrylidyne complexes -- An open-shell manganese stannylidyne comprising of a tin-centered unpaired electron -- u-Ylido complexes -- Chemistry of the metallatetrylidyne complexes -- Plumbylidyne transfer reaction -- Access to the first NHC-stabilized disilavinylidene -- Summary and Outlook -- Experimental Section.
Contained By:	Springer eBooks
標題:	Ligands. -
電子資源:	https://doi.org/10.1007/978-3-030-02625-7
ISBN:	9783030026257

Synthesis, characterization and reactivity of Ylidyne and μ-Ylido complexes supported by scorpionato ligands
Ghana, Priyabrata.

Synthesis, characterization and reactivity of Ylidyne and μ-Ylido complexes supported by scorpionato ligands[electronic resource] /by Priyabrata Ghana. - Cham :Springer International Publishing :2019. - xxii, 344 p. :ill. (some col.), digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction -- Closed shell heavier tetrylidyne complexes of group 6 metals -- Open-shell heavier tetrylidyne complexes of group 6 transition metals -- Germylidyne mediated C-C coupling reaction of isonitriles - formation of an N-heterocyclic germylene -- A new method for the synthesis of manganese tetrylidyne complexes -- An open-shell manganese stannylidyne comprising of a tin-centered unpaired electron -- u-Ylido complexes -- Chemistry of the metallatetrylidyne complexes -- Plumbylidyne transfer reaction -- Access to the first NHC-stabilized disilavinylidene -- Summary and Outlook -- Experimental Section.

This book explores the development of the first open-shell heavier tetrylidyne complexes featuring a tetrel-centered unpaired electron, and unprecedented metallatetrylidynes containing a multiply-bonded, linear-coordinated single heavier tetrel atom embedded between two metal centers. The chemistry of compounds featuring triple bonds of the heavier Group-14 elements Si-Pb with transition metals is a very challenging research area, which combines modern molecular main-group element with transition-metal chemistry, and is of fundamental importance for the understanding of chemical bonding. During the last 15 years, the research in this area has witnessed considerable progress in isolating a series of closed-shell tetrylidyne complexes. However, despite numerous attempts, open-shell tetrylidyne complexes and heavier group 14 element congeners of metallacarbynes and carbide complexes remained inaccessible. In this book, readers will find more about the synthesis, full characterization and reactivity studies of these novel complexes that uncovered a plethora of exceptional products, including a novel m3-silicido complex, the first dimetallasilacumulene with a linear, two-coordinated single silicon atom and the first compounds of planar tetracoordinated silicon (ptSi) (Anti-van't Hoff-Le Bell Silicon) Readers will also learn about the isolation and full characterization of the first room-temperature stable disilavinylidene, a silicon analogue of the very reactive vinylidenes (R2C=C:), and the first intermetallic plumbylidyne ligand transfer reactions.

ISBN: 9783030026257

Standard No.: 10.1007/978-3-030-02625-7doiSubjects--Topical Terms:

686413
Ligands.

LC Class. No.: QD474 / .G436 2019

Dewey Class. No.: 541.2242

Synthesis, characterization and reactivity of Ylidyne and μ-Ylido complexes supported by scorpionato ligands
LDR:03278nmm a2200337 a 4500 001 2178281
003 DE-He213
005 20190624103110.0
006 m d
007 cr nn 008maaau
008 191122s2019 gw s 0 eng d
020 $a 9783030026257 $q (electronic bk.)
020 $a 9783030026240 $q (paper)
024 7 $a 10.1007/978-3-030-02625-7 $2 doi
035 $a 978-3-030-02625-7
040 $a GP $c GP
041 0 $a eng
050 4 $a QD474 $b .G436 2019
072 7 $a PNND $2 bicssc
072 7 $a SCI013040 $2 bisacsh
072 7 $a PNND $2 thema
082 0 4 $a 541.2242 $2 23
090 $a QD474 $b .G411 2019
100 1 $a Ghana, Priyabrata. $3 3382288
245 1 0 $a Synthesis, characterization and reactivity of Ylidyne and μ-Ylido complexes supported by scorpionato ligands $h [electronic resource] / $c by Priyabrata Ghana.
260 $a Cham : $b Springer International Publishing : $b Imprint: Springer, $c 2019.
300 $a xxii, 344 p. : $b ill. (some col.), digital ; $c 24 cm.
490 1 $a Springer theses, $x 2190-5053
505 0 $a Introduction -- Closed shell heavier tetrylidyne complexes of group 6 metals -- Open-shell heavier tetrylidyne complexes of group 6 transition metals -- Germylidyne mediated C-C coupling reaction of isonitriles - formation of an N-heterocyclic germylene -- A new method for the synthesis of manganese tetrylidyne complexes -- An open-shell manganese stannylidyne comprising of a tin-centered unpaired electron -- u-Ylido complexes -- Chemistry of the metallatetrylidyne complexes -- Plumbylidyne transfer reaction -- Access to the first NHC-stabilized disilavinylidene -- Summary and Outlook -- Experimental Section.
520 $a This book explores the development of the first open-shell heavier tetrylidyne complexes featuring a tetrel-centered unpaired electron, and unprecedented metallatetrylidynes containing a multiply-bonded, linear-coordinated single heavier tetrel atom embedded between two metal centers. The chemistry of compounds featuring triple bonds of the heavier Group-14 elements Si-Pb with transition metals is a very challenging research area, which combines modern molecular main-group element with transition-metal chemistry, and is of fundamental importance for the understanding of chemical bonding. During the last 15 years, the research in this area has witnessed considerable progress in isolating a series of closed-shell tetrylidyne complexes. However, despite numerous attempts, open-shell tetrylidyne complexes and heavier group 14 element congeners of metallacarbynes and carbide complexes remained inaccessible. In this book, readers will find more about the synthesis, full characterization and reactivity studies of these novel complexes that uncovered a plethora of exceptional products, including a novel m3-silicido complex, the first dimetallasilacumulene with a linear, two-coordinated single silicon atom and the first compounds of planar tetracoordinated silicon (ptSi) (Anti-van't Hoff-Le Bell Silicon) Readers will also learn about the isolation and full characterization of the first room-temperature stable disilavinylidene, a silicon analogue of the very reactive vinylidenes (R2C=C:), and the first intermetallic plumbylidyne ligand transfer reactions.
650 0 $a Ligands. $3 686413
650 0 $a Silicon. $3 669429
650 1 4 $a Organometallic Chemistry. $3 892407
650 2 4 $a Inorganic Chemistry. $3 890827
650 2 4 $a Spectroscopy/Spectrometry. $3 1084899
710 2 $a SpringerLink (Online service) $3 836513
773 0 $t Springer eBooks
830 0 $a Springer theses. $3 1314442
856 4 0 $u https://doi.org/10.1007/978-3-030-02625-7
950 $a Chemistry and Materials Science (Springer-11644)