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Catalytic Asymmetric Desymmetrisatio...

Yi, Yi.

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Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization./
作者:	Yi, Yi.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, : 2018,
面頁冊數:	318 p.
附註:	Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
Contained By:	Dissertation Abstracts International79-09B(E).
標題:	Organic chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10786363
ISBN:	9780355890662

Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.
Yi, Yi.

Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization. - Ann Arbor : ProQuest Dissertations & Theses, 2018 - 318 p.

Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.

Thesis (Ph.D.)--Michigan State University, 2018.

My doctorate research work with professor Borhan is mainly focused on developing new asymmetric halofunctionalization reactions. Chapter 1 describes the catalytic asymmetric desymmetrisation of dienes via chlorocyclization. Chapter 2 describes the kinetic resolution of propargyl amides via chlorocyclization. Both desymmetrisation and kinetic resolution using cinchona alkaloid (DHQD) 2PHAL as catalyst afford good diastereoselectivity and enantioselectivity. Chapter 3 discloses efforts to develop asymmetric ipso-halocyclization via dearomatization of phenol derivatives. Chapter 4 describes a novel and practical method to access N,O-acetals using commercially available XtalFluor-ERTM as catalyst.

ISBN: 9780355890662Subjects--Topical Terms:

523952
Organic chemistry.

Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.
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