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High resolution imaging, spectroscop...

Guo, Jing.

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High resolution imaging, spectroscopy and nuclear quantum effects of interfacial water

Record Type:	Electronic resources : Monograph/item
Title/Author:	High resolution imaging, spectroscopy and nuclear quantum effects of interfacial water/ by Jing Guo.
Author:	Guo, Jing.
Published:	Singapore :Springer Singapore : : 2018.,
Description:	xviii, 115 p. :digital ;24 cm.
[NT 15003449]:	Introduction -- Submolecular resolution imaging of interfacial water -- Vibrational spectroscopy of interfacial water -- Nuclear quantum effects of interfacial water -- Summary and outlook.
Contained By:	Springer eBooks
Subject:	High resolution imaging. -
Online resource:	http://dx.doi.org/10.1007/978-981-13-1663-0
ISBN:	9789811316630

High resolution imaging, spectroscopy and nuclear quantum effects of interfacial water
Guo, Jing.

High resolution imaging, spectroscopy and nuclear quantum effects of interfacial water[electronic resource] /by Jing Guo. - Singapore :Springer Singapore :2018. - xviii, 115 p. :digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction -- Submolecular resolution imaging of interfacial water -- Vibrational spectroscopy of interfacial water -- Nuclear quantum effects of interfacial water -- Summary and outlook.

This thesis presents a series of experimental techniques based on scanning probe microscopy, which make it possible access the degree of freedom of protons both in real and energy space. These novel techniques and methods allow direct visualization of the concerted quantum tunneling of protons within the hydrogen-bonded network and quantification of the quantum component of a single hydrogen bond at a water-solid interface for the first time. Furthermore, the thesis demonstrates that the anharmonic quantum fluctuations of hydrogen nuclei further weaken the weak hydrogen bonds and strengthen the strong ones. However, this trend was reversed when the hydrogen bond coupled to the local environment. These pioneering findings substantially advance our understanding of the quantum nature of H bonds at the molecular level.

ISBN: 9789811316630

Standard No.: 10.1007/978-981-13-1663-0doiSubjects--Topical Terms:

2071658
High resolution imaging.

LC Class. No.: TA1637 / .G865 2018

Dewey Class. No.: 621.367

High resolution imaging, spectroscopy and nuclear quantum effects of interfacial water
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520 $a This thesis presents a series of experimental techniques based on scanning probe microscopy, which make it possible access the degree of freedom of protons both in real and energy space. These novel techniques and methods allow direct visualization of the concerted quantum tunneling of protons within the hydrogen-bonded network and quantification of the quantum component of a single hydrogen bond at a water-solid interface for the first time. Furthermore, the thesis demonstrates that the anharmonic quantum fluctuations of hydrogen nuclei further weaken the weak hydrogen bonds and strengthen the strong ones. However, this trend was reversed when the hydrogen bond coupled to the local environment. These pioneering findings substantially advance our understanding of the quantum nature of H bonds at the molecular level.
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650 0 $a Spectrum analysis. $3 520440
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650 2 4 $a Spectroscopy and Microscopy. $3 1066375
650 2 4 $a Atomic/Molecular Structure and Spectra. $3 1066408
650 2 4 $a Surface and Interface Science, Thin Films. $3 1244633
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