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Synthesis and characterization of "c...

Windham, Amber Danielle.

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Synthesis and characterization of "click-inspired" thiol-ene-fullerene nanocomposites.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Synthesis and characterization of "click-inspired" thiol-ene-fullerene nanocomposites./
Author:	Windham, Amber Danielle.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2016,
Description:	116 p.
Notes:	Source: Dissertation Abstracts International, Volume: 77-09(E), Section: B.
Contained By:	Dissertation Abstracts International77-09B(E).
Subject:	Chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10100043
ISBN:	9781339639819

Synthesis and characterization of "click-inspired" thiol-ene-fullerene nanocomposites.
Windham, Amber Danielle.

Synthesis and characterization of "click-inspired" thiol-ene-fullerene nanocomposites. - Ann Arbor : ProQuest Dissertations & Theses, 2016 - 116 p.

Source: Dissertation Abstracts International, Volume: 77-09(E), Section: B.

Thesis (Ph.D.)--The University of Southern Mississippi, 2016.

This item is not available from ProQuest Dissertations & Theses.

This work explores the covalent incorporation of C60 and Sc 3N C80 fullerenes into thiol-ene networks by a facile, one-pot photochemical reaction with multifunctional thiol and alkene monomers. Synthesis of disulfide bonds within the tri-functional thiol monomer served to photochemically initiate the reaction when cleaved. This was followed by thermal curing of the pre-polymer for preparation of fullerene-containing thiol-ene films. Films were characterized by standard techniques including infrared spectroscopy, gel percent, and thermogravimetric analysis. The role of C60 and Sc3N C80 as suitable alkenes for free-radical reaction with multifunctional thiols was investigated by preparing a series of thiol-films possessing a significant stoichiometric deficiency of alkyl ene monomer. Dynamic mechanical analysis of these films revealed an enhancement of the storage modulus values, increased glass transition temperatures, and increased network crosslink density with added C60 and Sc3N C80. Investigation of the fullerene dispersion throughout the polymer was performed by transmission electron microscopy and revealed no significant aggregation of C60 or Sc3N C80 in 1 wt % samples prepared by the pre-polymer method.

ISBN: 9781339639819Subjects--Topical Terms:

516420
Chemistry.

Synthesis and characterization of "click-inspired" thiol-ene-fullerene nanocomposites.
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245 1 0 $a Synthesis and characterization of "click-inspired" thiol-ene-fullerene nanocomposites.
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300 $a 116 p.
500 $a Source: Dissertation Abstracts International, Volume: 77-09(E), Section: B.
500 $a Adviser: J. Paige Buchanan.
502 $a Thesis (Ph.D.)--The University of Southern Mississippi, 2016.
506 $a This item is not available from ProQuest Dissertations & Theses.
520 $a This work explores the covalent incorporation of C60 and Sc 3N C80 fullerenes into thiol-ene networks by a facile, one-pot photochemical reaction with multifunctional thiol and alkene monomers. Synthesis of disulfide bonds within the tri-functional thiol monomer served to photochemically initiate the reaction when cleaved. This was followed by thermal curing of the pre-polymer for preparation of fullerene-containing thiol-ene films. Films were characterized by standard techniques including infrared spectroscopy, gel percent, and thermogravimetric analysis. The role of C60 and Sc3N C80 as suitable alkenes for free-radical reaction with multifunctional thiols was investigated by preparing a series of thiol-films possessing a significant stoichiometric deficiency of alkyl ene monomer. Dynamic mechanical analysis of these films revealed an enhancement of the storage modulus values, increased glass transition temperatures, and increased network crosslink density with added C60 and Sc3N C80. Investigation of the fullerene dispersion throughout the polymer was performed by transmission electron microscopy and revealed no significant aggregation of C60 or Sc3N C80 in 1 wt % samples prepared by the pre-polymer method.
520 $a To extend possible applications of this novel polymer nanocomposite, the preparation of fullerene-containing microspheres was pursued. An acoustic excitation coaxial flow (AECF) method was developed in this study to yield microspheres of narrow size dispersions. Microspheres were analyzed via optical microscopy, scanning electron microscopy, and dynamic light scattering. Microsphere production was determined to be dependent on the settings of the applied acoustic energy, as well as the viscosity of the discrete polymer solution, and flow rate of the non-solvent carrier phase. This presents the AECF method as a tunable technique for control of the microsphere diameter, with ability to prepare thiol-ene microspheres as small as 200 nm in diameter. C60 and Sc3N C80 thiol-ene microspheres were prepared and characterized by differential scanning calorimetry, thermogravimetric analysis, and optical microscopy.
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710 2 $a The University of Southern Mississippi. $b Chemistry & Biochemistry. $3 3282335
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