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Polymerizable lipids for controlled ...

Rupp, Kortney Kaye.

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Polymerizable lipids for controlled functionalization of layered materials.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Polymerizable lipids for controlled functionalization of layered materials./
作者:	Rupp, Kortney Kaye.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, : 2016,
面頁冊數:	69 p.
附註:	Source: Masters Abstracts International, Volume: 56-02.
Contained By:	Masters Abstracts International56-02(E).
標題:	Analytical chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10182204
ISBN:	9781369306132

Polymerizable lipids for controlled functionalization of layered materials.
Rupp, Kortney Kaye.

Polymerizable lipids for controlled functionalization of layered materials. - Ann Arbor : ProQuest Dissertations & Theses, 2016 - 69 p.

Source: Masters Abstracts International, Volume: 56-02.

Thesis (M.S.)--Purdue University, 2016.

Self-assembled monolayers (SAM's) offer a straightforward approach to tailoring the interfacial properties of metals, metal oxides and semiconductors. Noncovalent functionalization of single-layer graphene offers the possibility to finely tune surface chemistry for future applications in electronics. Polymerization of photochemically reactive molecules in a lying-down phase has been used to increase the strength of intermolecular interactions between long alkanes and HOPG substrates. Long-chain fatty acid derivatives with internal diyne groups yield a conjugated ene-yne polymer upon UV irradiation. Diyne lipids with phosphocholine (diyne PC) and phosphoethanolamine (diyne PE) groups offer a charged form of the head group that is robust towards solvents and contain photopolymerizable diyne groups within the acyl chains. The orientation of polymerizable phospholipids on HOPG was assessed by matching dimensions from AFM images of the observed lamellar features. Molecular modeling provided insight into the interactions occurring between head groups and tail groups along with presenting ideas about the molecular alignment of the lipids on the HOPG substrate, before and after polymerization. The films were assessed for solvent stability and for the ability to template deposition of other small molecules.

ISBN: 9781369306132Subjects--Topical Terms:

3168300
Analytical chemistry.

Polymerizable lipids for controlled functionalization of layered materials.
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