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Metal-organic Frameworks, including ...

Phan, Anh Thi Phuong.

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Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation./
Author:	Phan, Anh Thi Phuong.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2011,
Description:	258 p.
Notes:	Source: Dissertation Abstracts International, Volume: 73-05, Section: B, page: 2938.
Contained By:	Dissertation Abstracts International73-05B.
Subject:	Organic chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3493501
ISBN:	9781267144430

Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation.
Phan, Anh Thi Phuong.

Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation. - Ann Arbor : ProQuest Dissertations & Theses, 2011 - 258 p.

Source: Dissertation Abstracts International, Volume: 73-05, Section: B, page: 2938.

Thesis (Ph.D.)--University of California, Los Angeles, 2011.

Although a large segment of the economy is based on porous materials, it generally remains a long challenge to produce porous materials designed to have a well-defined structure, tunable metrics, organic functionality and high stability and porosity, to perform highly specific and cooperative functions. Additionally, the synthesis of these compounds has mostly been unpredictable, tedious and time consuming. For decades, this type of synthesis has worked well for the discovery of important porous materials. However, it is becoming increasingly urgent to facilitate the discovery of these porous materials, especially for applications which address the global warning issues such as CO2 sequestration and methane activation.

ISBN: 9781267144430Subjects--Topical Terms:

523952
Organic chemistry.

Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation.
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100 1 $a Phan, Anh Thi Phuong. $3 3278672
245 1 0 $a Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2011
300 $a 258 p.
500 $a Source: Dissertation Abstracts International, Volume: 73-05, Section: B, page: 2938.
500 $a Adviser: Omar M. Yaghi.
502 $a Thesis (Ph.D.)--University of California, Los Angeles, 2011.
520 $a Although a large segment of the economy is based on porous materials, it generally remains a long challenge to produce porous materials designed to have a well-defined structure, tunable metrics, organic functionality and high stability and porosity, to perform highly specific and cooperative functions. Additionally, the synthesis of these compounds has mostly been unpredictable, tedious and time consuming. For decades, this type of synthesis has worked well for the discovery of important porous materials. However, it is becoming increasingly urgent to facilitate the discovery of these porous materials, especially for applications which address the global warning issues such as CO2 sequestration and methane activation.
520 $a This thesis focuses on a developed of high-throughput synthesis protocol which overcomes the barriers found in traditional synthesis methodologies. Using high-throughput method, twenty-five zeolitic imidazolate frameworks (ZIFs) have been synthesized with structures based on zeolite topologies. These 25 ZIFs have a variety of functions and structures, are chemically and thermally stable and their syntheses are reproducible. Members of these ZIFs, termed ZIF-68, 69 and 70, demonstrated high capacity for sequestering CO 2 and they selectively capture CO2 for the practical application of reducing carbon dioxide emissions.
520 $a This thesis has also focused on applying the concepts of a well-defined pore structure, tunable pore metrics, high stability and porosity of metal-organic frameworks (MOFs) to contribute to the discovery of highly active and selective heterogeneous MOF catalysts in methane activation. MIL-47 and MOF-48 catalysts have been found to directly convert methane to acetic acid with 72% yield, 490 TON and 100% selectivity. These MOF catalysts are structurally stable under catalytic conditions, are reusable and are easy to separate. They remain catalytically active for several recycling steps. Their performances exceeded the reported heterogeneous catalyst systems for the direct conversion of methane to acetic acid.
590 $a School code: 0031.
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650 4 $a Inorganic chemistry. $3 3173556
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773 0 $t Dissertation Abstracts International $g 73-05B.
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793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3493501