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Design, synthesis, characterization,...

Lanni, Laura M.

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Design, synthesis, characterization, and evaluation of boronate ester-linked porous materials: Covalent organic frameworks and polymers of intrinsic microporosity.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Design, synthesis, characterization, and evaluation of boronate ester-linked porous materials: Covalent organic frameworks and polymers of intrinsic microporosity./
Author:	Lanni, Laura M.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2010,
Description:	200 p.
Notes:	Source: Dissertation Abstracts International, Volume: 72-02, Section: B, page: 8970.
Contained By:	Dissertation Abstracts International72-02B.
Subject:	Organic chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3433161
ISBN:	9781124384313

Design, synthesis, characterization, and evaluation of boronate ester-linked porous materials: Covalent organic frameworks and polymers of intrinsic microporosity.
Lanni, Laura M.

Design, synthesis, characterization, and evaluation of boronate ester-linked porous materials: Covalent organic frameworks and polymers of intrinsic microporosity. - Ann Arbor : ProQuest Dissertations & Theses, 2010 - 200 p.

Source: Dissertation Abstracts International, Volume: 72-02, Section: B, page: 8970.

Thesis (Ph.D.)--University of South Carolina, 2010.

An array of porous boronate ester-linked materials is presented here. Beginning with evaluation of a series of alkylated covalent organic frameworks (COFs), insight into the influence of alkylation in the hexagonal COF pores on the hydrolytic stability of the B-O linkages led to development of a family of hybrid COFs (HCOFs). These HCOFs were made by incorporating a gradual ladder of alkylation into the COF pores and provided a synthetic method to dial in stability along with porosity for specific COF applications. Parallel research resulted in a new COF with incorporated phthalocyanine groups (CuPC-COF) which could lead to future semiconducting thin films. The synthetic strategy to produce an octahydroxy-phthalocyanine monomer and the typical COF characterizations of PXRD and gas uptake are reported.

ISBN: 9781124384313Subjects--Topical Terms:

523952
Organic chemistry.

Design, synthesis, characterization, and evaluation of boronate ester-linked porous materials: Covalent organic frameworks and polymers of intrinsic microporosity.
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245 1 0 $a Design, synthesis, characterization, and evaluation of boronate ester-linked porous materials: Covalent organic frameworks and polymers of intrinsic microporosity.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2010
300 $a 200 p.
500 $a Source: Dissertation Abstracts International, Volume: 72-02, Section: B, page: 8970.
500 $a Adviser: John J. Lavigne.
502 $a Thesis (Ph.D.)--University of South Carolina, 2010.
520 $a An array of porous boronate ester-linked materials is presented here. Beginning with evaluation of a series of alkylated covalent organic frameworks (COFs), insight into the influence of alkylation in the hexagonal COF pores on the hydrolytic stability of the B-O linkages led to development of a family of hybrid COFs (HCOFs). These HCOFs were made by incorporating a gradual ladder of alkylation into the COF pores and provided a synthetic method to dial in stability along with porosity for specific COF applications. Parallel research resulted in a new COF with incorporated phthalocyanine groups (CuPC-COF) which could lead to future semiconducting thin films. The synthetic strategy to produce an octahydroxy-phthalocyanine monomer and the typical COF characterizations of PXRD and gas uptake are reported.
520 $a The newest materials produced are porous yet amorphous and are the first family of boronate ester-linked polymers of intrinsic microporosity (PIMs). This family utilized the kink in a spirobisindane bis-diol monomer along with linear and trigonal boronic acids to produce amorphous solids which are intrinsically microporous. The potential of these materials to form permeable membranes and gas storage/separation devices, along with an abundant list of alternative commercially available monomers, warrant further development and testing of these boronate ester-linked PIMs.
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