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Electrons, Protons, and Solvents in ...

Gregory Arthur Pilgrim.

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Electrons, Protons, and Solvents in Carbon Nanotubes.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Electrons, Protons, and Solvents in Carbon Nanotubes./
Author:	Gregory Arthur Pilgrim.
Description:	171 p.
Notes:	Source: Dissertation Abstracts International, Volume: 77-01(E), Section: B.
Contained By:	Dissertation Abstracts International77-01B(E).
Subject:	Nanotechnology. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3723303
ISBN:	9781339060286

Electrons, Protons, and Solvents in Carbon Nanotubes.
Gregory Arthur Pilgrim.

Electrons, Protons, and Solvents in Carbon Nanotubes. - 171 p.

Source: Dissertation Abstracts International, Volume: 77-01(E), Section: B.

Thesis (Ph.D.)--University of Rochester, 2015.

This item is not available from ProQuest Dissertations & Theses.

The two regimes of carbon nanotubes -- wall and bore -- provide two distinct environments. The extended pi structure of nanotube walls was used to transport electrons at energy levels dependent on the wall chirality. The empty bore was used to host solvent molecules and provide a pathway for proton transport. Simultaneous transport of both charged species was measured in a donor-acceptor system inspired by photosynthesis in plants and aimed at storing solar energy in chemical fuel. Transport was observed spectroscopically through use of indicator molecules. The interaction of solvent molecules in the bore with the confinement imposed by the walls was also probed by x-ray diffraction at low temperature. Confined molecules and their interactions have implications for areas as diverse as protein folding and geology.

ISBN: 9781339060286Subjects--Topical Terms:

526235
Nanotechnology.

Electrons, Protons, and Solvents in Carbon Nanotubes.
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245 1 0 $a Electrons, Protons, and Solvents in Carbon Nanotubes.
300 $a 171 p.
500 $a Source: Dissertation Abstracts International, Volume: 77-01(E), Section: B.
500 $a Adviser: Todd Krauss.
502 $a Thesis (Ph.D.)--University of Rochester, 2015.
506 $a This item is not available from ProQuest Dissertations & Theses.
520 $a The two regimes of carbon nanotubes -- wall and bore -- provide two distinct environments. The extended pi structure of nanotube walls was used to transport electrons at energy levels dependent on the wall chirality. The empty bore was used to host solvent molecules and provide a pathway for proton transport. Simultaneous transport of both charged species was measured in a donor-acceptor system inspired by photosynthesis in plants and aimed at storing solar energy in chemical fuel. Transport was observed spectroscopically through use of indicator molecules. The interaction of solvent molecules in the bore with the confinement imposed by the walls was also probed by x-ray diffraction at low temperature. Confined molecules and their interactions have implications for areas as diverse as protein folding and geology.
590 $a School code: 0188.
650 4 $a Nanotechnology. $3 526235
650 4 $a Materials science. $3 543314
650 4 $a Nanoscience. $3 587832
690 $a 0652
690 $a 0794
690 $a 0565
710 2 $a University of Rochester. $b Arts and Sciences. $3 3171976
773 0 $t Dissertation Abstracts International $g 77-01B(E).
790 $a 0188
791 $a Ph.D.
792 $a 2015
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3723303