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Electrochemistry and photoelectroche...

Llorente, Mark Justin.

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Electrochemistry and photoelectrochemistry in carbon cycle relevant energy systems.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Electrochemistry and photoelectrochemistry in carbon cycle relevant energy systems./
作者:	Llorente, Mark Justin.
面頁冊數:	135 p.
附註:	Source: Dissertation Abstracts International, Volume: 77-12(E), Section: B.
Contained By:	Dissertation Abstracts International77-12B(E).
標題:	Materials science. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10128281
ISBN:	9781339862934

Electrochemistry and photoelectrochemistry in carbon cycle relevant energy systems.
Llorente, Mark Justin.

Electrochemistry and photoelectrochemistry in carbon cycle relevant energy systems. - 135 p.

Source: Dissertation Abstracts International, Volume: 77-12(E), Section: B.

Thesis (Ph.D.)--University of California, San Diego, 2016.

To create fully sustainable energy systems requires multiple stages of engagement across different fields. The work presented in this dissertation represents a small survey of two major branches of sustainable chemistry---the improved efficiency for converting from renewably sourced fuels to power and the utilization of renewable sources of electricity to produce valuable chemicals from renewable carbon feedstocks. Electrochemistry and photoelectrochemistry are powerful tools for interconversion between chemical and electrical energy and for using light to drive chemical change.

ISBN: 9781339862934Subjects--Topical Terms:

543314
Materials science.

Electrochemistry and photoelectrochemistry in carbon cycle relevant energy systems.
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245 1 0 $a Electrochemistry and photoelectrochemistry in carbon cycle relevant energy systems.
300 $a 135 p.
500 $a Source: Dissertation Abstracts International, Volume: 77-12(E), Section: B.
500 $a Adviser: Clifford P. Kubiak.
502 $a Thesis (Ph.D.)--University of California, San Diego, 2016.
520 $a To create fully sustainable energy systems requires multiple stages of engagement across different fields. The work presented in this dissertation represents a small survey of two major branches of sustainable chemistry---the improved efficiency for converting from renewably sourced fuels to power and the utilization of renewable sources of electricity to produce valuable chemicals from renewable carbon feedstocks. Electrochemistry and photoelectrochemistry are powerful tools for interconversion between chemical and electrical energy and for using light to drive chemical change.
520 $a Light can be used to overcome both the kinetic and thermodynamic barriers found in electrochemistry. In a proposed fuel cell device, the feasibility of using multi-carbon fuels like n-hexane at ambient temperatures and pressures may be made possible by using light activated materials to overcome the kinetic barriers to fuel oxidation. The energy to produce the light may be sourced from the fuel cell itself and fed back into the oxidation process. In an electrolysis reaction, light may be used to drive the uphill reaction by creating sufficient photovoltage and photocurrent. In a paired electrolysis, CO2 and a lignin derived substrate syringaldehyde are simultaneously upgraded using a customized photovoltaic device to drive both catalytic processes. In both of these implementations, electricity plays the crucial role of connecting light energy to chemical change and provides two examples where it can be used in sustainable chemical methods.
590 $a School code: 0033.
650 4 $a Materials science. $3 543314
650 4 $a Inorganic chemistry. $3 3173556
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710 2 $a University of California, San Diego. $b Materials Sci and Engineering. $3 1023651
773 0 $t Dissertation Abstracts International $g 77-12B(E).
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793 $a English
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