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Surface Chemistry Studies of Transit...

Li, Zhisheng.

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Surface Chemistry Studies of Transition Metal Oxides: Titanium Oxide and Iron Oxide.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Surface Chemistry Studies of Transition Metal Oxides: Titanium Oxide and Iron Oxide./
Author:	Li, Zhisheng.
Description:	152 p.
Notes:	Source: Dissertation Abstracts International, Volume: 76-09(E), Section: B.
Contained By:	Dissertation Abstracts International76-09B(E).
Subject:	Physical chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3689457
ISBN:	9781321688498

Surface Chemistry Studies of Transition Metal Oxides: Titanium Oxide and Iron Oxide.
Li, Zhisheng.

Surface Chemistry Studies of Transition Metal Oxides: Titanium Oxide and Iron Oxide. - 152 p.

Source: Dissertation Abstracts International, Volume: 76-09(E), Section: B.

Thesis (Ph.D.)--Columbia University, 2015.

Surface chemistry studies of two transition-metal oxides: titanium oxide and iron oxide are presented, which are focused on thermal induced chemistry using proximal probe imaging and spectroscopy. In the first, using single crystal of rutile TiO2 (110), arrays of nano-scale locally varying surface strain field were generated by introducing highly pressurized nanoscale argon clusters 4-11 layers below the surface. The characteristics of the argon clusters are explored through STM tip-assisted surface excavation, combining with a continuum mechanical model. This work experimentally demonstrates that surface elastic strain influences the adsorption energy of adsorbates significantly and, thus, can be used for applications of surface nanopatterning. As a comparison with work on nanoscale, two forms of titanium oxide in reduced dimensionalities are experimentally synthesized and investigated for their surface reactivity: 3D nano TiO2 crystals and monolayer TiO films, both of which are supported on single crystal Au(111) surface. This work demonstrates that both nano crystals and ultrathin films of titanium oxide exhibit distinctive surface structural and catalytic properties compared to the bulk surface terminations. In particular, TiO2 nano crystals are more catalytically active and provide a new dissociation channel for adsorbed 2-propanol, a probe molecule chosen for this study. In the process of undertaking this research, it was found that monolayer TiO film can be used to employ moire varied chemistry. In particular, a long range pinwheel-shaped surface moire pattern due to gradual shift of atom registry on Au (111), was found to further influence the adsorption geometry of adsorbates and to cause thereby smoothly varying sites for reactions.

ISBN: 9781321688498Subjects--Topical Terms:

1981412
Physical chemistry.

Surface Chemistry Studies of Transition Metal Oxides: Titanium Oxide and Iron Oxide.
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100 1 $a Li, Zhisheng. $3 3192928
245 1 0 $a Surface Chemistry Studies of Transition Metal Oxides: Titanium Oxide and Iron Oxide.
300 $a 152 p.
500 $a Source: Dissertation Abstracts International, Volume: 76-09(E), Section: B.
500 $a Adviser: Richard M. Osgood.
502 $a Thesis (Ph.D.)--Columbia University, 2015.
520 $a Surface chemistry studies of two transition-metal oxides: titanium oxide and iron oxide are presented, which are focused on thermal induced chemistry using proximal probe imaging and spectroscopy. In the first, using single crystal of rutile TiO2 (110), arrays of nano-scale locally varying surface strain field were generated by introducing highly pressurized nanoscale argon clusters 4-11 layers below the surface. The characteristics of the argon clusters are explored through STM tip-assisted surface excavation, combining with a continuum mechanical model. This work experimentally demonstrates that surface elastic strain influences the adsorption energy of adsorbates significantly and, thus, can be used for applications of surface nanopatterning. As a comparison with work on nanoscale, two forms of titanium oxide in reduced dimensionalities are experimentally synthesized and investigated for their surface reactivity: 3D nano TiO2 crystals and monolayer TiO films, both of which are supported on single crystal Au(111) surface. This work demonstrates that both nano crystals and ultrathin films of titanium oxide exhibit distinctive surface structural and catalytic properties compared to the bulk surface terminations. In particular, TiO2 nano crystals are more catalytically active and provide a new dissociation channel for adsorbed 2-propanol, a probe molecule chosen for this study. In the process of undertaking this research, it was found that monolayer TiO film can be used to employ moire varied chemistry. In particular, a long range pinwheel-shaped surface moire pattern due to gradual shift of atom registry on Au (111), was found to further influence the adsorption geometry of adsorbates and to cause thereby smoothly varying sites for reactions.
520 $a In the case, of the second transition metal oxide surface, Fe3O 4 (111), a comparison was made with rutile TiO2 (110) surface, Fe3O4 (111) is a polar surface with apparent surface charge, and thus undergoes various surface reconstructions. Therefore, its surface structure is of great complexity. Our work shows that the reaction of methanol on this iron-oxide surface is highly sensitive to atomic-level surface reconstructions.
590 $a School code: 0054.
650 4 $a Physical chemistry. $3 1981412
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710 2 $a Columbia University. $b Applied Physics. $3 3187824
773 0 $t Dissertation Abstracts International $g 76-09B(E).
790 $a 0054
791 $a Ph.D.
792 $a 2015
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3689457