東華大學圖書館 |

Language: English

Help

回圖書館首頁

手機版館藏查詢

Back

Switch To: Labeled | MARC Mode | ISBD

Designing Metal-Organic Frameworks w...

Yao, Bin.

Linked to FindBook

Google Book

Amazon

博客來

Designing Metal-Organic Frameworks with Hierarchical Structure.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Designing Metal-Organic Frameworks with Hierarchical Structure./
Author:	Yao, Bin.
Description:	46 p.
Notes:	Source: Masters Abstracts International, Volume: 52-02.
Contained By:	Masters Abstracts International52-02(E).
Subject:	Inorganic chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1543141
ISBN:	9781303290145

Designing Metal-Organic Frameworks with Hierarchical Structure.
Yao, Bin.

Designing Metal-Organic Frameworks with Hierarchical Structure. - 46 p.

Source: Masters Abstracts International, Volume: 52-02.

Thesis (M.S.)--University of South Dakota, 2013.

Metal-organic frameworks (MOFs) are hybrid crystalline materials composed of metal ions and organic bridging ligands. MOFs have a variety of potential applications, including gas storage, separation, catalysis, and drug delivery. This work focuses on designing new MOFs with hierarchical pore structures.

ISBN: 9781303290145Subjects--Topical Terms:

3173556
Inorganic chemistry.

Designing Metal-Organic Frameworks with Hierarchical Structure.
LDR:02153nmm a2200289 4500 001 2069994
005 20160602092034.5
008 170521s2013 ||||||||||||||||| ||eng d
020 $a 9781303290145
035 $a (MiAaPQ)AAI1543141
035 $a AAI1543141
040 $a MiAaPQ $c MiAaPQ
100 1 $a Yao, Bin. $3 3185008
245 1 0 $a Designing Metal-Organic Frameworks with Hierarchical Structure.
300 $a 46 p.
500 $a Source: Masters Abstracts International, Volume: 52-02.
500 $a Adviser: Andrew Sykes.
502 $a Thesis (M.S.)--University of South Dakota, 2013.
520 $a Metal-organic frameworks (MOFs) are hybrid crystalline materials composed of metal ions and organic bridging ligands. MOFs have a variety of potential applications, including gas storage, separation, catalysis, and drug delivery. This work focuses on designing new MOFs with hierarchical pore structures.
520 $a In particular, a new magnesium MOF was constructed from a tetracarboxylate ligand and in-situ formed magnesium carboxylate clusters. The structure of the magnesium MOF was fully characterized by single-crystal X-ray crystallography, powder X-ray diffraction, thermal gravimetric analysis, and gas adsorption analysis. The MOF was found to be significantly porous to both N2 and CO2. The design of hierarchical MOFs based on tetra nuclear sulfonylcalixarene complexes was also attempted. A tetranuclear precursor based on cobalt (II) acetate and p-tert-butylsulfonyl calix[4]arene was synthesized following a modified literature procedure.
520 $a Compared to the crystal structure described in the literature, the Co-precursor synthesized in this thesis work has a subtly different crystal packing. The Co-precursor was characterized by single-crystal X-ray crystallography, powder X-ray diffraction, and thermal gravimetric analysis and its utility as a building block to construct hierarchical MOFs was examined.
590 $a School code: 0203.
650 4 $a Inorganic chemistry. $3 3173556
690 $a 0488
710 2 $a University of South Dakota. $b Chemistry. $3 1679392
773 0 $t Masters Abstracts International $g 52-02(E).
790 $a 0203
791 $a M.S.
792 $a 2013
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1543141