語系:
繁體中文
English
說明(常見問題)
回圖書館首頁
手機版館藏查詢
登入
回首頁
切換:
標籤
|
MARC模式
|
ISBD
Catalytic Enantioselective Formation...
~
Wu, Hao.
FindBook
Google Book
Amazon
博客來
Catalytic Enantioselective Formations of C-B, C-C and C-Si Bonds by Organic Molecules or Transition-Metal Complexes.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Catalytic Enantioselective Formations of C-B, C-C and C-Si Bonds by Organic Molecules or Transition-Metal Complexes./
作者:
Wu, Hao.
面頁冊數:
632 p.
附註:
Source: Dissertation Abstracts International, Volume: 77-03(E), Section: B.
Contained By:
Dissertation Abstracts International77-03B(E).
標題:
Organic chemistry. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3732584
ISBN:
9781339204871
Catalytic Enantioselective Formations of C-B, C-C and C-Si Bonds by Organic Molecules or Transition-Metal Complexes.
Wu, Hao.
Catalytic Enantioselective Formations of C-B, C-C and C-Si Bonds by Organic Molecules or Transition-Metal Complexes.
- 632 p.
Source: Dissertation Abstracts International, Volume: 77-03(E), Section: B.
Thesis (Ph.D.)--Boston College, 2015.
Catalytic enantioselective reactions are of great importance in synthetic organic chemistry. Thus, development of efficient, selective and easily accessible catalyst for various bond formations is the main task in our laboratories.
ISBN: 9781339204871Subjects--Topical Terms:
523952
Organic chemistry.
Catalytic Enantioselective Formations of C-B, C-C and C-Si Bonds by Organic Molecules or Transition-Metal Complexes.
LDR
:02182nmm a2200301 4500
001
2067761
005
20160418090201.5
008
170521s2015 ||||||||||||||||| ||eng d
020
$a
9781339204871
035
$a
(MiAaPQ)AAI3732584
035
$a
AAI3732584
040
$a
MiAaPQ
$c
MiAaPQ
100
1
$a
Wu, Hao.
$3
1678939
245
1 0
$a
Catalytic Enantioselective Formations of C-B, C-C and C-Si Bonds by Organic Molecules or Transition-Metal Complexes.
300
$a
632 p.
500
$a
Source: Dissertation Abstracts International, Volume: 77-03(E), Section: B.
500
$a
Adviser: Amir H. Hoveyda.
502
$a
Thesis (Ph.D.)--Boston College, 2015.
520
$a
Catalytic enantioselective reactions are of great importance in synthetic organic chemistry. Thus, development of efficient, selective and easily accessible catalyst for various bond formations is the main task in our laboratories.
520
$a
First, we have developed the first broadly applicable enantioselective boryl conjugate addition reactions to a variety of alpha,beta-unsaturated carbonyls, promoted by a chiral Lewis basic N-heterocyclic carbene. The valuable beta-boryl carbonyls were further used in complex molecule syntheses. The mechanism of these C--B bond formations was studied in details.
520
$a
We have also developed a practical method for enantioselective addition of an allene unit to aryl-, heteroaryl- and alkyl-substituted Boc-aldimines. These efficient C--C bond formations, catalyzed by an aminophenol-derived boron-based catalyst, were further utilized in succinct syntheses of anisomycin and epi-cytoxazone.
520
$a
Finally, chiral NHC--Cu complexes were employed for site-, diastereo- and enantioselective silyl conjugate additions to acyclic and cyclic dienones and dienoates. The precious enantiomerically enriched allylsilane obtained can be converted into a ketone-aldol type product, which is difficult to access through alternative methods.
590
$a
School code: 0016.
650
4
$a
Organic chemistry.
$3
523952
690
$a
0490
710
2
$a
Boston College.
$b
Chemistry.
$3
3182627
773
0
$t
Dissertation Abstracts International
$g
77-03B(E).
790
$a
0016
791
$a
Ph.D.
792
$a
2015
793
$a
English
856
4 0
$u
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3732584
筆 0 讀者評論
館藏地:
全部
電子資源
出版年:
卷號:
館藏
1 筆 • 頁數 1 •
1
條碼號
典藏地名稱
館藏流通類別
資料類型
索書號
使用類型
借閱狀態
預約狀態
備註欄
附件
W9300629
電子資源
11.線上閱覽_V
電子書
EB
一般使用(Normal)
在架
0
1 筆 • 頁數 1 •
1
多媒體
評論
新增評論
分享你的心得
Export
取書館
處理中
...
變更密碼
登入