東華大學圖書館 |

語系: 繁體中文

說明(常見問題)

回圖書館首頁

手機版館藏查詢

登入

回首頁

切換: 標籤 | MARC模式 | ISBD

The development of rhodium-catalyzed...

Annis, Alexandra Helen.

FindBook

Google Book

Amazon

博客來

The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes./
作者:	Annis, Alexandra Helen.
面頁冊數:	84 p.
附註:	Source: Masters Abstracts International, Volume: 55-01.
Contained By:	Masters Abstracts International55-01(E).
標題:	Organic chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1598129
ISBN:	9781339024134

The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes.
Annis, Alexandra Helen.

The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes. - 84 p.

Source: Masters Abstracts International, Volume: 55-01.

Thesis (M.S.)--Boston College, 2015.

Asymmetric hydroformylation (AHF) is a metal-catalyzed reaction in which CO and H2 are added across an olefin to form a new carbon-carbon bond. AHF has perfect atom-economy and is an ideal way to form a chiral aldehyde. However, the utility of branch selective hydroformylation is limited due to a lack of readily available ligands and restrictions on a wide variety of terminal olefins. Herein, Rh-catalyzed asymmetric hydroformylation of 1-alkenes is reported using commercially available Ph-BPE ligand to generate alpha-chiral aldehydes. A wide range of terminal olefins were explored and all showed high enantioselectivity (up to 98:2 er) and good regioselectivity (up to 15:1 branched to linear ratio).

ISBN: 9781339024134Subjects--Topical Terms:

523952
Organic chemistry.

The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes.
LDR:01550nmm a2200265 4500 001 2067642
005 20160418090141.5
008 170521s2015 ||||||||||||||||| ||eng d
020 $a 9781339024134
035 $a (MiAaPQ)AAI1598129
035 $a AAI1598129
040 $a MiAaPQ $c MiAaPQ
100 1 $a Annis, Alexandra Helen. $3 3182502
245 1 4 $a The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes.
300 $a 84 p.
500 $a Source: Masters Abstracts International, Volume: 55-01.
500 $a Adviser: James P. Morken.
502 $a Thesis (M.S.)--Boston College, 2015.
520 $a Asymmetric hydroformylation (AHF) is a metal-catalyzed reaction in which CO and H2 are added across an olefin to form a new carbon-carbon bond. AHF has perfect atom-economy and is an ideal way to form a chiral aldehyde. However, the utility of branch selective hydroformylation is limited due to a lack of readily available ligands and restrictions on a wide variety of terminal olefins. Herein, Rh-catalyzed asymmetric hydroformylation of 1-alkenes is reported using commercially available Ph-BPE ligand to generate alpha-chiral aldehydes. A wide range of terminal olefins were explored and all showed high enantioselectivity (up to 98:2 er) and good regioselectivity (up to 15:1 branched to linear ratio).
590 $a School code: 0016.
650 4 $a Organic chemistry. $3 523952
690 $a 0490
710 2 $a Boston College. $b GSAS - Chemistry. $3 2094863
773 0 $t Masters Abstracts International $g 55-01(E).
790 $a 0016
791 $a M.S.
792 $a 2015
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1598129