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Copper-Mediated Oxidative Decarboxyl...

Ju, Lin.

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Copper-Mediated Oxidative Decarboxylative Coupling Reactions: Trifluoromethylation of Heteroarene C-H bonds with Trifluoroacetic Acid as the CF3 Source and C-H Arylation of Benzoxazoles with Benzoic Acids.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Copper-Mediated Oxidative Decarboxylative Coupling Reactions: Trifluoromethylation of Heteroarene C-H bonds with Trifluoroacetic Acid as the CF3 Source and C-H Arylation of Benzoxazoles with Benzoic Acids./
作者:	Ju, Lin.
面頁冊數:	43 p.
附註:	Source: Masters Abstracts International, Volume: 54-04.
Contained By:	Masters Abstracts International54-04(E).
標題:	Organic chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1588084
ISBN:	9781321729689

Copper-Mediated Oxidative Decarboxylative Coupling Reactions: Trifluoromethylation of Heteroarene C-H bonds with Trifluoroacetic Acid as the CF3 Source and C-H Arylation of Benzoxazoles with Benzoic Acids.
Ju, Lin.

Copper-Mediated Oxidative Decarboxylative Coupling Reactions: Trifluoromethylation of Heteroarene C-H bonds with Trifluoroacetic Acid as the CF3 Source and C-H Arylation of Benzoxazoles with Benzoic Acids. - 43 p.

Source: Masters Abstracts International, Volume: 54-04.

Thesis (M.S.)--West Virginia University, 2015.

Compared with the prefunctionalized substrates in traditional cross-coupling reactions, carboxylic acid derivatives are easier to handle and commercially available in a broad scope, making them ideal starting materials to build biaryl structures. Copper has been demonstrated to decarboxylate carboxylic acids. There are also several examples of copper-mediated oxidative coupling reactions with two nucleophilic components. However, the copper-mediated direct C-H trifluoromethylation and arylation of heteroarenes with trifluoroacetic acid and benzoic acids is still challenging.

ISBN: 9781321729689Subjects--Topical Terms:

523952
Organic chemistry.

Copper-Mediated Oxidative Decarboxylative Coupling Reactions: Trifluoromethylation of Heteroarene C-H bonds with Trifluoroacetic Acid as the CF3 Source and C-H Arylation of Benzoxazoles with Benzoic Acids.
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245 1 0 $a Copper-Mediated Oxidative Decarboxylative Coupling Reactions: Trifluoromethylation of Heteroarene C-H bonds with Trifluoroacetic Acid as the CF3 Source and C-H Arylation of Benzoxazoles with Benzoic Acids.
300 $a 43 p.
500 $a Source: Masters Abstracts International, Volume: 54-04.
500 $a Adviser: Jessica Hoover.
502 $a Thesis (M.S.)--West Virginia University, 2015.
520 $a Compared with the prefunctionalized substrates in traditional cross-coupling reactions, carboxylic acid derivatives are easier to handle and commercially available in a broad scope, making them ideal starting materials to build biaryl structures. Copper has been demonstrated to decarboxylate carboxylic acids. There are also several examples of copper-mediated oxidative coupling reactions with two nucleophilic components. However, the copper-mediated direct C-H trifluoromethylation and arylation of heteroarenes with trifluoroacetic acid and benzoic acids is still challenging.
520 $a This thesis is divided into three chapters. Chapter I and Chapter II will describe copper-mediated oxidative decarboxylative trifluoromethylation of C-H bonds, including heteroarenes and arenes bearing a directing group, with trifluoroacetic acid as the trifluoromethylating reagent. Chapter III will focus on the catalytic synthesis of biaryl structures by copper-catalyzed decarboxylative cross-coupling with benzoic acids and benzoxazoles.
590 $a School code: 0256.
650 4 $a Organic chemistry. $3 523952
690 $a 0490
710 2 $a West Virginia University. $b Eberly College of Arts & Sciences. $3 2099039
773 0 $t Masters Abstracts International $g 54-04(E).
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791 $a M.S.
792 $a 2015
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1588084