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Environmentally Responsive Hydrogels...

Chatterjee, Prithwish.

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Environmentally Responsive Hydrogels: Development and Integration with Hard Materials.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Environmentally Responsive Hydrogels: Development and Integration with Hard Materials./
作者:	Chatterjee, Prithwish.
面頁冊數:	170 p.
附註:	Source: Dissertation Abstracts International, Volume: 77-04(E), Section: B.
Contained By:	Dissertation Abstracts International77-04B(E).
標題:	Chemical engineering. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3735190
ISBN:	9781339240039

Environmentally Responsive Hydrogels: Development and Integration with Hard Materials.
Chatterjee, Prithwish.

Environmentally Responsive Hydrogels: Development and Integration with Hard Materials. - 170 p.

Source: Dissertation Abstracts International, Volume: 77-04(E), Section: B.

Thesis (Ph.D.)--Arizona State University, 2015.

Environmentally responsive hydrogels are one interesting class of soft materials. Due to their remarkable responsiveness to stimuli such as temperature, pH, or light, they have attracted widespread attention in many fields. However, certain functionality of these materials alone is often limited in comparison to other materials such as silicon; thus, there is a need to integrate soft and hard materials for the advancement of environmentally responsive materials.

ISBN: 9781339240039Subjects--Topical Terms:

560457
Chemical engineering.

Environmentally Responsive Hydrogels: Development and Integration with Hard Materials.
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245 1 0 $a Environmentally Responsive Hydrogels: Development and Integration with Hard Materials.
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500 $a Source: Dissertation Abstracts International, Volume: 77-04(E), Section: B.
500 $a Advisers: Lenore L. Dai; Hanqing Jiang.
502 $a Thesis (Ph.D.)--Arizona State University, 2015.
520 $a Environmentally responsive hydrogels are one interesting class of soft materials. Due to their remarkable responsiveness to stimuli such as temperature, pH, or light, they have attracted widespread attention in many fields. However, certain functionality of these materials alone is often limited in comparison to other materials such as silicon; thus, there is a need to integrate soft and hard materials for the advancement of environmentally responsive materials.
520 $a Conventional hydrogels lack good mechanical properties and have inherently slow response time, important characteristics which must be improved before the hydrogels can be integrated with silicon. In the present dissertation work, both these important attributes of a temperature responsive hydrogel, poly(N-isopropylacrylamide) (PNIPAAm), were improved by adopting a low temperature polymerization process and adding a silicate compound, tetramethyl orthosilicate. Furthermore, the transition temperature was modulated by adjusting the media quality in which the hydrogels were equilibrated, e.g. by adding a co-solvent (methanol) or an anionic surfactant (sodium dodecyl sulfate). Interestingly, the results revealed that, based on the hydrogels' porosity, there were appreciable differences when the PNIPAAm hydrogels interacted with the media molecules.
520 $a Next, an adhesion mechanism was developed in order to transfer silicon thin film onto the hydrogel surface. This integration provided a means of mechanical buckling of the thin silicon film due to changes in environmental stimuli (e.g., temperature, pH). We also investigated how novel transfer printing techniques could be used to generate patterned deformation of silicon thin film when integrated on a planar hydrogel substrate. Furthermore, we explore multilayer hybrid hydrogel structures formed by the integration of different types of hydrogels that have tunable curvatures under the influence of different stimuli. Silicon thin film integration on such tunable curvature substrates reveal characteristic reversible buckling of the thin film in the presence of multiple stimuli.
520 $a Finally, different approaches of incorporating visible light response in PNIPAAm are discussed. Specifically, a chemical chromophore- spirobenzopyran was synthesized and integrated through chemical cross-linking into the PNIPAAm hydrogels. Further, methods of improving the light response and mechanical properties were also demonstrated. Interestingly, such a system was shown to have potential application as light modulated topography altering system.
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