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Application of photoacoustic, photot...

Isak, Stefan Johan.

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Application of photoacoustic, photothermal and fluorescence spectroscopies in signal enhancement and the kinetics, chemistry and photophysics of several dyes.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Application of photoacoustic, photothermal and fluorescence spectroscopies in signal enhancement and the kinetics, chemistry and photophysics of several dyes./
Author:	Isak, Stefan Johan.
Description:	199 p.
Notes:	Source: Dissertation Abstracts International, Volume: 53-03, Section: B, page: 1388.
Contained By:	Dissertation Abstracts International53-03B.
Subject:	Physical chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=9221723

Application of photoacoustic, photothermal and fluorescence spectroscopies in signal enhancement and the kinetics, chemistry and photophysics of several dyes.
Isak, Stefan Johan.

Application of photoacoustic, photothermal and fluorescence spectroscopies in signal enhancement and the kinetics, chemistry and photophysics of several dyes. - 199 p.

Source: Dissertation Abstracts International, Volume: 53-03, Section: B, page: 1388.

Thesis (Ph.D.)--The University of Utah, 1992.

Photothermal and photoacoustic phenomena are consequences of nonradiative, heat releasing processes that occur upon relaxation of an excited molecule. When a molecule absorbs energy, as through excitation with a laser light source, heat releasing processes such as internal conversion and intersystem crossing will result in the formation of a pressure wave due to a change in the local density due to solvent heating and the production of a thermal gradient due to local heating of the solvent. By monitoring the magnitude and/or time profile of such heat releasing processes by a substance or substances after absorption of exciting radiation, quantum yields, lifetimes and a wide variety of kinetic and photophysical or photochemical parameters of a solute molecule or system of molecules may be determined.Subjects--Topical Terms:

1981412
Physical chemistry.

Application of photoacoustic, photothermal and fluorescence spectroscopies in signal enhancement and the kinetics, chemistry and photophysics of several dyes.
LDR:03462nmm a2200301 4500 001 2064155
005 20151109121437.5
008 170521s1992 ||||||||||||||||| ||eng d
035 $a (MiAaPQ)AAI9221723
035 $a AAI9221723
040 $a MiAaPQ $c MiAaPQ
100 1 $a Isak, Stefan Johan. $3 3178716
245 1 0 $a Application of photoacoustic, photothermal and fluorescence spectroscopies in signal enhancement and the kinetics, chemistry and photophysics of several dyes.
300 $a 199 p.
500 $a Source: Dissertation Abstracts International, Volume: 53-03, Section: B, page: 1388.
500 $a Chairperson: Edward M. Eyring.
502 $a Thesis (Ph.D.)--The University of Utah, 1992.
520 $a Photothermal and photoacoustic phenomena are consequences of nonradiative, heat releasing processes that occur upon relaxation of an excited molecule. When a molecule absorbs energy, as through excitation with a laser light source, heat releasing processes such as internal conversion and intersystem crossing will result in the formation of a pressure wave due to a change in the local density due to solvent heating and the production of a thermal gradient due to local heating of the solvent. By monitoring the magnitude and/or time profile of such heat releasing processes by a substance or substances after absorption of exciting radiation, quantum yields, lifetimes and a wide variety of kinetic and photophysical or photochemical parameters of a solute molecule or system of molecules may be determined.
520 $a A number of modifications to conventional photoacoustic and photothermal spectroscopies are applied in analytical studies of liquid and solid systems. The quenching of benzophenone by potassium iodide is used to demonstrate the application of time resolved photothermal spectroscopies in the study of fast (submicrosecond) deexcitation processes. Inherently weak X-ray photoacoustic signals at a synchrotron are enhanced by the introduction of a volatile liquid into a gas-microphone photoacoustic cell.
520 $a Traditionally, photoacoustic signals have been detected either by gas coupling with a microphone or with a piezoelectric detector. However, optically detected photoacoustic signals have been used in the determination of physical properties of a liquid sample system and are successfully applied to the study of deexcitation processes of a number of dye molecules. Photothermal beam deflection photoacoustic (PBDPA), fluorescence and absorbance measurements are utilized to study the chemistry and photophysics of cresyl violet in aqueous, aqueous micellar and methanolic solutions. A previously unrecognized concentration dependence of the fluorescence quantum yield of cresyl violet is thoroughly investigated.
520 $a Aspects of the chemistry and photophysics relating to the potential use of several diazo dyes as photothermal sensitizing dyes in photodynamic therapy are explored experimentally and discussed. Photothermal beam deflection, fluorescence and absorbance measurements are again utilized. The dyes are found to have a number of interesting chemical and photophysical properties. They are also determined to be ideal photothermal sensitizing dye candidates.
590 $a School code: 0240.
650 4 $a Physical chemistry. $3 1981412
650 4 $a Analytical chemistry. $3 3168300
690 $a 0494
690 $a 0486
710 2 $a The University of Utah. $3 1017410
773 0 $t Dissertation Abstracts International $g 53-03B.
790 $a 0240
791 $a Ph.D.
792 $a 1992
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=9221723