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Part I. Transition Metal Cross Coupl...

Graham, Thomas James Albert.

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Part I. Transition Metal Cross Coupling with Iminium and Oxocarbenium Ions. Part II. Enantioselective Radiosynthesis of PET Tracers Containing [18F]Fluorohydrins.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Part I. Transition Metal Cross Coupling with Iminium and Oxocarbenium Ions. Part II. Enantioselective Radiosynthesis of PET Tracers Containing [18F]Fluorohydrins./
Author:	Graham, Thomas James Albert.
Description:	201 p.
Notes:	Source: Dissertation Abstracts International, Volume: 75-10(E), Section: B.
Contained By:	Dissertation Abstracts International75-10B(E).
Subject:	Organic chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3626653
ISBN:	9781321016697

Part I. Transition Metal Cross Coupling with Iminium and Oxocarbenium Ions. Part II. Enantioselective Radiosynthesis of PET Tracers Containing [18F]Fluorohydrins.
Graham, Thomas James Albert.

Part I. Transition Metal Cross Coupling with Iminium and Oxocarbenium Ions. Part II. Enantioselective Radiosynthesis of PET Tracers Containing [18F]Fluorohydrins. - 201 p.

Source: Dissertation Abstracts International, Volume: 75-10(E), Section: B.

Thesis (Ph.D.)--Princeton University, 2014.

This item must not be sold to any third party vendors.

Part I of this thesis will cover the discovery of a Ni-catalyzed cross coupling reaction between N-acyliminium ions derived from quinoline and isoquinoline-based N,O-acetals and arylboronic acids. A detailed treatment of the optimization of this reaction along with its scope will be presented. Additionally, details of the mechanism through several studies will be presented. Finally, a brief discussion of progress toward rendering this method enantioselective will be considered. The second section of Part I will cover a Ni-catalyzed cross-coupling reaction between oxocarbenium ions derived from chromene acetals and arylboronic acids. A detailed treatment of the optimization of this reaction along with its scope will be presented. Additionally, details of the mechanism through several studies will be presented alongside progress toward rendering this reaction asymmetric.

ISBN: 9781321016697Subjects--Topical Terms:

523952
Organic chemistry.

Part I. Transition Metal Cross Coupling with Iminium and Oxocarbenium Ions. Part II. Enantioselective Radiosynthesis of PET Tracers Containing [18F]Fluorohydrins.
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100 1 $a Graham, Thomas James Albert. $3 3173967
245 1 0 $a Part I. Transition Metal Cross Coupling with Iminium and Oxocarbenium Ions. Part II. Enantioselective Radiosynthesis of PET Tracers Containing [18F]Fluorohydrins.
300 $a 201 p.
500 $a Source: Dissertation Abstracts International, Volume: 75-10(E), Section: B.
500 $a Adviser: Abigail G. Doyle.
502 $a Thesis (Ph.D.)--Princeton University, 2014.
506 $a This item must not be sold to any third party vendors.
520 $a Part I of this thesis will cover the discovery of a Ni-catalyzed cross coupling reaction between N-acyliminium ions derived from quinoline and isoquinoline-based N,O-acetals and arylboronic acids. A detailed treatment of the optimization of this reaction along with its scope will be presented. Additionally, details of the mechanism through several studies will be presented. Finally, a brief discussion of progress toward rendering this method enantioselective will be considered. The second section of Part I will cover a Ni-catalyzed cross-coupling reaction between oxocarbenium ions derived from chromene acetals and arylboronic acids. A detailed treatment of the optimization of this reaction along with its scope will be presented. Additionally, details of the mechanism through several studies will be presented alongside progress toward rendering this reaction asymmetric.
520 $a Part II of this thesis will focus on the development of an enantioselective radiofluorination of epoxides with [18F]fluoride. A brief description of the practical applications of PET will be considered in addition to optimization studies and scope of the developed method.
590 $a School code: 0181.
650 4 $a Organic chemistry. $3 523952
690 $a 0490
710 2 $a Princeton University. $b Chemistry. $3 2094742
773 0 $t Dissertation Abstracts International $g 75-10B(E).
790 $a 0181
791 $a Ph.D.
792 $a 2014
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3626653