東華大學圖書館 |

Language: English

Help

回圖書館首頁

手機版館藏查詢

Back

Switch To: Labeled | MARC Mode | ISBD

The chemistry of zirconacycles and 2...

Zhang, Shaoguang.

Linked to FindBook

Google Book

Amazon

博客來

The chemistry of zirconacycles and 2,6-diazasemibullvalenes = synthesis, structures, reactions, and applications in the synthesis of novel N-heterocycles /

Record Type:	Electronic resources : Monograph/item
Title/Author:	The chemistry of zirconacycles and 2,6-diazasemibullvalenes/ by Shaoguang Zhang.
Reminder of title:	synthesis, structures, reactions, and applications in the synthesis of novel N-heterocycles /
Author:	Zhang, Shaoguang.
Published:	Berlin, Heidelberg :Springer Berlin Heidelberg : : 2015.,
Description:	xi, 173 p. :ill. (some col.), digital ;24 cm.
[NT 15003449]:	Introduction to Zirconacycle Chemistry -- Zirconocene-Mediated Cyclization of Bis(alkynyl)silanes and Nitriles: Synthesis of N-Heterocycles and Isolation, Characterization and Synthetic Application of Zr/Si-containing Reactive Intermediates -- Bulky-Nitrile Coordination Induced Skeleton Rearrangement of Zr/Si-containing Metallacycles and Selective Synthesis of 5-Azaindoles -- Introduction to Semibullvalenes and Azasemibullvalenes -- 2,6-Diazasemibullvalenes: Synthesis, Structure, Theoretical Analysis and Computational Chemistry -- 2,6-Diazasemibullvalenes: Reaction Chemistry and Synthetic Application.
Contained By:	Springer eBooks
Subject:	Organometallic compounds. -
Online resource:	http://dx.doi.org/10.1007/978-3-662-45021-5
ISBN:	9783662450215 (electronic bk.)

The chemistry of zirconacycles and 2,6-diazasemibullvalenes = synthesis, structures, reactions, and applications in the synthesis of novel N-heterocycles /
Zhang, Shaoguang.

The chemistry of zirconacycles and 2,6-diazasemibullvalenessynthesis, structures, reactions, and applications in the synthesis of novel N-heterocycles /[electronic resource] :by Shaoguang Zhang. - Berlin, Heidelberg :Springer Berlin Heidelberg :2015. - xi, 173 p. :ill. (some col.), digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction to Zirconacycle Chemistry -- Zirconocene-Mediated Cyclization of Bis(alkynyl)silanes and Nitriles: Synthesis of N-Heterocycles and Isolation, Characterization and Synthetic Application of Zr/Si-containing Reactive Intermediates -- Bulky-Nitrile Coordination Induced Skeleton Rearrangement of Zr/Si-containing Metallacycles and Selective Synthesis of 5-Azaindoles -- Introduction to Semibullvalenes and Azasemibullvalenes -- 2,6-Diazasemibullvalenes: Synthesis, Structure, Theoretical Analysis and Computational Chemistry -- 2,6-Diazasemibullvalenes: Reaction Chemistry and Synthetic Application.

In this thesis, the author introduces two strategies used to construct various types of N-heterocycles, based on the chemistry of zirconacycles and 2,6-diazasemibullvalenes. In the first part, the author presents the development of multi-component cyclization of a zirconacyclobutene-silacyclobutene fused compound, nitriles and unsaturated compounds. These reactions provide synthetically useful methodology for various N-heterocycles such as 3-acyl pyrrole, pyrrolo[3,2-d]pyridazine and dihydropyrroloazepine, which are all difficult to synthesize by other means. The isolation and characterization of the key three-fused-ring Zr/Si-containing intermediates are also described in detail. These results show that the zirconacyclobutene-silacyclobutene fused compound behaves as a chemical transformer upon treatment with various substrates via the coordination-induced skeleton rearrangement mechanism. In the second part, the author demonstrates the synthesis and isolation of a series of 2,6-diazasemibullvalenes (NSBVs) from the reaction of 1,4-dilithio-1,3-dienes and nitriles, highlighting the significant progress made for the first time in this work: (1) determination of X-ray crystal structure of a substituted 2,6-diazasemibullvalene; (2) measurement of the activation barrier of its rapid intramolecular aza-Cope rearrangement in solution; (3) exploration of several reaction types of NSBV with diverse ring-expansion products and bowl-shape or cage-shape N-containing polycyclic skeletons; (4) demonstration of the localized structure as the predominant form and the homoaromatic delocalized structure as a minor component in the equilibrium using theoretical analysis. Based on well-founded results, this work sheds new light on this controversial topic.

ISBN: 9783662450215 (electronic bk.)

Standard No.: 10.1007/978-3-662-45021-5doiSubjects--Topical Terms:

560494
Organometallic compounds.

LC Class. No.: QD411 / .Z43 2015

Dewey Class. No.: 547.05

The chemistry of zirconacycles and 2,6-diazasemibullvalenes = synthesis, structures, reactions, and applications in the synthesis of novel N-heterocycles /
LDR:03491nmm a2200325 a 4500 001 1993460
003 DE-He213
005 20150703140710.0
006 m d
007 cr nn 008maaau
008 151019s2015 gw s 0 eng d
020 $a 9783662450215 (electronic bk.)
020 $a 9783662450208 (paper)
024 7 $a 10.1007/978-3-662-45021-5 $2 doi
035 $a 978-3-662-45021-5
040 $a GP $c GP
041 0 $a eng
050 4 $a QD411 $b .Z43 2015
072 7 $a PNND $2 bicssc
072 7 $a SCI013040 $2 bisacsh
082 0 4 $a 547.05 $2 23
090 $a QD411 $b .Z63 2015
100 1 $a Zhang, Shaoguang. $3 2131704
245 1 4 $a The chemistry of zirconacycles and 2,6-diazasemibullvalenes $h [electronic resource] : $b synthesis, structures, reactions, and applications in the synthesis of novel N-heterocycles / $c by Shaoguang Zhang.
260 $a Berlin, Heidelberg : $b Springer Berlin Heidelberg : $b Imprint: Springer, $c 2015.
300 $a xi, 173 p. : $b ill. (some col.), digital ; $c 24 cm.
490 1 $a Springer theses, $x 2190-5053
505 0 $a Introduction to Zirconacycle Chemistry -- Zirconocene-Mediated Cyclization of Bis(alkynyl)silanes and Nitriles: Synthesis of N-Heterocycles and Isolation, Characterization and Synthetic Application of Zr/Si-containing Reactive Intermediates -- Bulky-Nitrile Coordination Induced Skeleton Rearrangement of Zr/Si-containing Metallacycles and Selective Synthesis of 5-Azaindoles -- Introduction to Semibullvalenes and Azasemibullvalenes -- 2,6-Diazasemibullvalenes: Synthesis, Structure, Theoretical Analysis and Computational Chemistry -- 2,6-Diazasemibullvalenes: Reaction Chemistry and Synthetic Application.
520 $a In this thesis, the author introduces two strategies used to construct various types of N-heterocycles, based on the chemistry of zirconacycles and 2,6-diazasemibullvalenes. In the first part, the author presents the development of multi-component cyclization of a zirconacyclobutene-silacyclobutene fused compound, nitriles and unsaturated compounds. These reactions provide synthetically useful methodology for various N-heterocycles such as 3-acyl pyrrole, pyrrolo[3,2-d]pyridazine and dihydropyrroloazepine, which are all difficult to synthesize by other means. The isolation and characterization of the key three-fused-ring Zr/Si-containing intermediates are also described in detail. These results show that the zirconacyclobutene-silacyclobutene fused compound behaves as a chemical transformer upon treatment with various substrates via the coordination-induced skeleton rearrangement mechanism. In the second part, the author demonstrates the synthesis and isolation of a series of 2,6-diazasemibullvalenes (NSBVs) from the reaction of 1,4-dilithio-1,3-dienes and nitriles, highlighting the significant progress made for the first time in this work: (1) determination of X-ray crystal structure of a substituted 2,6-diazasemibullvalene; (2) measurement of the activation barrier of its rapid intramolecular aza-Cope rearrangement in solution; (3) exploration of several reaction types of NSBV with diverse ring-expansion products and bowl-shape or cage-shape N-containing polycyclic skeletons; (4) demonstration of the localized structure as the predominant form and the homoaromatic delocalized structure as a minor component in the equilibrium using theoretical analysis. Based on well-founded results, this work sheds new light on this controversial topic.
650 0 $a Organometallic compounds. $3 560494
650 1 4 $a Chemistry. $3 516420
650 2 4 $a Organometallic Chemistry. $3 892407
650 2 4 $a Physical Chemistry. $3 890828
650 2 4 $a Theoretical and Computational Chemistry. $3 890863
650 2 4 $a Crystallography. $3 518393
710 2 $a SpringerLink (Online service) $3 836513
773 0 $t Springer eBooks
830 0 $a Springer theses. $3 1314442
856 4 0 $u http://dx.doi.org/10.1007/978-3-662-45021-5
950 $a Chemistry and Materials Science (Springer-11644)