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Group IV metals in multi-electron re...

Jones, Mary E.

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Group IV metals in multi-electron reactions and kinetics of 1-hexene polymerization.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Group IV metals in multi-electron reactions and kinetics of 1-hexene polymerization./
Author:	Jones, Mary E.
Description:	111 p.
Notes:	Source: Dissertation Abstracts International, Volume: 74-12(E), Section: B.
Contained By:	Dissertation Abstracts International74-12B(E).
Subject:	Chemistry, Inorganic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3591292
ISBN:	9781303318528

Group IV metals in multi-electron reactions and kinetics of 1-hexene polymerization.
Jones, Mary E.

Group IV metals in multi-electron reactions and kinetics of 1-hexene polymerization. - 111 p.

Source: Dissertation Abstracts International, Volume: 74-12(E), Section: B.

Thesis (Ph.D.)--Purdue University, 2013.

Two investigative projects are presented. The synthesis and characterization of a series of novel complexes; two zirconium complexes and one titanium analog is presented using redox-active ligands. Zirconium was bound to two redox-active ligands in a tetrahedral structure. This complex reacts with molecular oxygen to form a bis-peroxo complex. An octahedral complex is formed where each peroxo occupies one site. The zirconium retains a 4+ oxidation state; the electrons required come from the now oxidized ligands. The eta2 bisperoxos are perpendicular to each other. The titanium analog does not react with molecular oxygen to form a peroxo complex.

ISBN: 9781303318528Subjects--Topical Terms:

517253
Chemistry, Inorganic.

Group IV metals in multi-electron reactions and kinetics of 1-hexene polymerization.
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008 150210s2013 ||||||||||||||||| ||eng d
020 $a 9781303318528
035 $a (MiAaPQ)AAI3591292
035 $a AAI3591292
040 $a MiAaPQ $c MiAaPQ
100 1 $a Jones, Mary E. $3 2099339
245 1 0 $a Group IV metals in multi-electron reactions and kinetics of 1-hexene polymerization.
300 $a 111 p.
500 $a Source: Dissertation Abstracts International, Volume: 74-12(E), Section: B.
500 $a Adviser: Mahdi M. Abu-Omar.
502 $a Thesis (Ph.D.)--Purdue University, 2013.
520 $a Two investigative projects are presented. The synthesis and characterization of a series of novel complexes; two zirconium complexes and one titanium analog is presented using redox-active ligands. Zirconium was bound to two redox-active ligands in a tetrahedral structure. This complex reacts with molecular oxygen to form a bis-peroxo complex. An octahedral complex is formed where each peroxo occupies one site. The zirconium retains a 4+ oxidation state; the electrons required come from the now oxidized ligands. The eta2 bisperoxos are perpendicular to each other. The titanium analog does not react with molecular oxygen to form a peroxo complex.
520 $a The polymerization kinetics and mechanism of a salan-based zirconium catalyst with 1-hexene were studied. The catalyst features bromo-substituents on the aromatic rings and benzyls as the leaving group. Monomer consumption kinetics, end group and active site analysis were done. Molecular weight distributions and modeling were employed to determine the mechanism. The polymerization was determined to have large chain transfer and little misinsertion. The polymer chains were of similar lengths regardless of the initial conditions.
590 $a School code: 0183.
650 4 $a Chemistry, Inorganic. $3 517253
650 4 $a Chemistry, Polymer. $3 1018428
690 $a 0488
690 $a 0495
710 2 $a Purdue University. $b Chemistry. $3 1019176
773 0 $t Dissertation Abstracts International $g 74-12B(E).
790 $a 0183
791 $a Ph.D.
792 $a 2013
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3591292