東華大學圖書館 |

語系: 繁體中文

說明(常見問題)

回圖書館首頁

手機版館藏查詢

登入

回首頁

切換: 標籤 | MARC模式 | ISBD

Theoretical Characterization of Bloc...

Pike, Darin Q.

FindBook

Google Book

Amazon

博客來

Theoretical Characterization of Block Copolymer Blends For Applications in Directed Self-Assembly.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Theoretical Characterization of Block Copolymer Blends For Applications in Directed Self-Assembly./
作者:	Pike, Darin Q.
面頁冊數:	88 p.
附註:	Source: Dissertation Abstracts International, Volume: 72-10, Section: B, page: 6193.
Contained By:	Dissertation Abstracts International72-10B.
標題:	Engineering, Chemical. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3471502
ISBN:	9781124828169

Theoretical Characterization of Block Copolymer Blends For Applications in Directed Self-Assembly.
Pike, Darin Q.

Theoretical Characterization of Block Copolymer Blends For Applications in Directed Self-Assembly. - 88 p.

Source: Dissertation Abstracts International, Volume: 72-10, Section: B, page: 6193.

Thesis (Ph.D.)--The University of Wisconsin - Madison, 2011.

Block copolymers are theoretically characterized using the self-consistent field theory and a Monte Carlo and dynamic approach inspired by the self-consistent field theory. The self-consistent field theory approach is used to evaluate a ternary system of diblock copolymers with each homopolymer. Swelling effects and phase behavior are studied in both the bulk and thin films.

ISBN: 9781124828169Subjects--Topical Terms:

1018531
Engineering, Chemical.

Theoretical Characterization of Block Copolymer Blends For Applications in Directed Self-Assembly.
LDR:02975nam a2200325 4500 001 1961779
005 20140722092938.5
008 150210s2011 ||||||||||||||||| ||eng d
020 $a 9781124828169
035 $a (MiAaPQ)AAI3471502
035 $a AAI3471502
040 $a MiAaPQ $c MiAaPQ
100 1 $a Pike, Darin Q. $3 2097725
245 1 0 $a Theoretical Characterization of Block Copolymer Blends For Applications in Directed Self-Assembly.
300 $a 88 p.
500 $a Source: Dissertation Abstracts International, Volume: 72-10, Section: B, page: 6193.
500 $a Adviser: Juan J. de Pablo.
502 $a Thesis (Ph.D.)--The University of Wisconsin - Madison, 2011.
520 $a Block copolymers are theoretically characterized using the self-consistent field theory and a Monte Carlo and dynamic approach inspired by the self-consistent field theory. The self-consistent field theory approach is used to evaluate a ternary system of diblock copolymers with each homopolymer. Swelling effects and phase behavior are studied in both the bulk and thin films.
520 $a A particle-based Monte Carlo formalism for the study of polymeric melts is derived from the local density functional that appears in the field-based model. The model is particle-based but the interaction is derived from a local density functional that appears in the field-based model. The method enables Monte Carlo simulations in the nVT, nPT, semi-grandcanonical and Gibbs ensembles and direct calculation of free energies. In the first use of this approach, we consider the phase separation of a binary homopolymer blend and present results for the phase diagram and the critical point. Next, we address the microphase separation of a symmetric diblock copolymer, examine the distribution of local stresses in lamellae and determine the order-disorder transition temperature.
520 $a Our third Monte-Carlo study is in the nPT-ensemble and the Gibbs ensemble on symmetric ternary mixtures of AB-diblock copolymers with the corresponding homopolymers. We study the lamellar period by varying the length and amount of homopolymers. The homopolymer distribution within the lamellar morphology is determined as is the maximum amount of homopolymer within the lamellae. Gibbs ensemble simulations are used to locate the three-phase coexistence between two homopolymer-rich phases and a lamellar phase. We discuss the implications of the results with respect to short-range wetting phenomena and long-range van-der-Waals interactions.
520 $a Finally, the particle-based approach is extended to a dynamic study with shear. Bond length and mean-square displacement are investigated, and shear's effect on phase behavior is dismissed.
590 $a School code: 0262.
650 4 $a Engineering, Chemical. $3 1018531
650 4 $a Chemistry, Polymer. $3 1018428
650 4 $a Physics, Condensed Matter. $3 1018743
690 $a 0542
690 $a 0495
690 $a 0611
710 2 $a The University of Wisconsin - Madison. $3 626640
773 0 $t Dissertation Abstracts International $g 72-10B.
790 $a 0262
791 $a Ph.D.
792 $a 2011
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3471502