語系:
繁體中文
English
說明(常見問題)
回圖書館首頁
手機版館藏查詢
登入
回首頁
切換:
標籤
|
MARC模式
|
ISBD
Synthesis and characterisation of n-...
~
Swidan, Ala'aeddeen.
FindBook
Google Book
Amazon
博客來
Synthesis and characterisation of n-heterocyclic carbene adducts of pi cations.
紀錄類型:
書目-語言資料,印刷品 : Monograph/item
正題名/作者:
Synthesis and characterisation of n-heterocyclic carbene adducts of pi cations./
作者:
Swidan, Ala'aeddeen.
面頁冊數:
105 p.
附註:
Source: Masters Abstracts International, Volume: 52-03.
Contained By:
Masters Abstracts International52-03(E).
標題:
Chemistry, General. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=MR87397
ISBN:
9780494873977
Synthesis and characterisation of n-heterocyclic carbene adducts of pi cations.
Swidan, Ala'aeddeen.
Synthesis and characterisation of n-heterocyclic carbene adducts of pi cations.
- 105 p.
Source: Masters Abstracts International, Volume: 52-03.
Thesis (M.Sc.)--University of Windsor (Canada), 2013.
The Macdonald research group has long been interested in the synthesis of compounds containing low-valent main group elements. Recently, more work was put forth in the synthesis and study of molecules containing phosphorous in its +1 oxidation state (PI). One way of stabilizing the PI center is by using N-heterocyclic carbenes (NHCs). Our group previously reported several approaches to salts containing [(RNHC R')2PI]+ cations, most notably through ligand replacement reactions from precursors such as [(dppe)P I]+ that we had developed previously. Various derivatives of cyclic [(RBis)PI] and acyclic [(R NHCR')2PI]+ compounds have been synthesized. Experimental and computational investigation of the structural features, physical properties and reactivity patterns of such species are discussed. Evidence of pi-delocalization from the electron rich phosphorus into the pi-system is detailed with the cyclic system giving better delocalization due to the more planar arrangement forced by the bridging methylene. Oxidation and metal coordination reactions are performed on such compounds.
ISBN: 9780494873977Subjects--Topical Terms:
1021807
Chemistry, General.
Synthesis and characterisation of n-heterocyclic carbene adducts of pi cations.
LDR
:01960nam a2200277 4500
001
1961021
005
20140701144904.5
008
150210s2013 ||||||||||||||||| ||eng d
020
$a
9780494873977
035
$a
(MiAaPQ)AAIMR87397
035
$a
AAIMR87397
040
$a
MiAaPQ
$c
MiAaPQ
100
1
$a
Swidan, Ala'aeddeen.
$3
2096832
245
1 0
$a
Synthesis and characterisation of n-heterocyclic carbene adducts of pi cations.
300
$a
105 p.
500
$a
Source: Masters Abstracts International, Volume: 52-03.
500
$a
Adviser: Charles L. B. Macdonald.
502
$a
Thesis (M.Sc.)--University of Windsor (Canada), 2013.
520
$a
The Macdonald research group has long been interested in the synthesis of compounds containing low-valent main group elements. Recently, more work was put forth in the synthesis and study of molecules containing phosphorous in its +1 oxidation state (PI). One way of stabilizing the PI center is by using N-heterocyclic carbenes (NHCs). Our group previously reported several approaches to salts containing [(RNHC R')2PI]+ cations, most notably through ligand replacement reactions from precursors such as [(dppe)P I]+ that we had developed previously. Various derivatives of cyclic [(RBis)PI] and acyclic [(R NHCR')2PI]+ compounds have been synthesized. Experimental and computational investigation of the structural features, physical properties and reactivity patterns of such species are discussed. Evidence of pi-delocalization from the electron rich phosphorus into the pi-system is detailed with the cyclic system giving better delocalization due to the more planar arrangement forced by the bridging methylene. Oxidation and metal coordination reactions are performed on such compounds.
590
$a
School code: 0115.
650
4
$a
Chemistry, General.
$3
1021807
650
4
$a
Chemistry, Inorganic.
$3
517253
690
$a
0485
690
$a
0488
710
2
$a
University of Windsor (Canada).
$b
CHEMISTRY AND BIOCHEMISTRY.
$3
2096833
773
0
$t
Masters Abstracts International
$g
52-03(E).
790
$a
0115
791
$a
M.Sc.
792
$a
2013
793
$a
English
856
4 0
$u
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=MR87397
筆 0 讀者評論
館藏地:
全部
電子資源
出版年:
卷號:
館藏
1 筆 • 頁數 1 •
1
條碼號
典藏地名稱
館藏流通類別
資料類型
索書號
使用類型
借閱狀態
預約狀態
備註欄
附件
W9255849
電子資源
11.線上閱覽_V
電子書
EB
一般使用(Normal)
在架
0
1 筆 • 頁數 1 •
1
多媒體
評論
新增評論
分享你的心得
Export
取書館
處理中
...
變更密碼
登入