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Synthesis and characterization of ch...

Laughlin, Brynna Jayne.

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Synthesis and characterization of chromophores and semiconducting polymers incorporating a 1,4-fluorenylene scaffold.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Synthesis and characterization of chromophores and semiconducting polymers incorporating a 1,4-fluorenylene scaffold./
Author:	Laughlin, Brynna Jayne.
Description:	265 p.
Notes:	Source: Dissertation Abstracts International, Volume: 74-10(E), Section: B.
Contained By:	Dissertation Abstracts International74-10B(E).
Subject:	Chemistry, General. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3565115
ISBN:	9781303146213

Synthesis and characterization of chromophores and semiconducting polymers incorporating a 1,4-fluorenylene scaffold.
Laughlin, Brynna Jayne.

Synthesis and characterization of chromophores and semiconducting polymers incorporating a 1,4-fluorenylene scaffold. - 265 p.

Source: Dissertation Abstracts International, Volume: 74-10(E), Section: B.

Thesis (Ph.D.)--Clemson University, 2013.

Research on conjugated chromophores and polymers has been a lucrative and highly active area for over a quarter-century. These pursuits have been driven by the unique properties of conjugated systems that allow their application in myriad fields including photonics (e.g. non-linear optics), and especially optoelectronics (e.g. organic light emitting diodes (OLEDs) and photovoltaic (PV) cells). Despite the years of dedicated research, there is still much work to be done in developing better materials for these types of applications. The full range of available molecular architecture and functionalization that are yet to be explored is still an untapped well of research.

ISBN: 9781303146213Subjects--Topical Terms:

1021807
Chemistry, General.

Synthesis and characterization of chromophores and semiconducting polymers incorporating a 1,4-fluorenylene scaffold.
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020 $a 9781303146213
035 $a (MiAaPQ)AAI3565115
035 $a AAI3565115
040 $a MiAaPQ $c MiAaPQ
100 1 $a Laughlin, Brynna Jayne. $3 2096480
245 1 0 $a Synthesis and characterization of chromophores and semiconducting polymers incorporating a 1,4-fluorenylene scaffold.
300 $a 265 p.
500 $a Source: Dissertation Abstracts International, Volume: 74-10(E), Section: B.
500 $a Adviser: Rhett C. Smith.
502 $a Thesis (Ph.D.)--Clemson University, 2013.
520 $a Research on conjugated chromophores and polymers has been a lucrative and highly active area for over a quarter-century. These pursuits have been driven by the unique properties of conjugated systems that allow their application in myriad fields including photonics (e.g. non-linear optics), and especially optoelectronics (e.g. organic light emitting diodes (OLEDs) and photovoltaic (PV) cells). Despite the years of dedicated research, there is still much work to be done in developing better materials for these types of applications. The full range of available molecular architecture and functionalization that are yet to be explored is still an untapped well of research.
520 $a To this end, the research presented here aims to explore a particular scaffold, a 1,4-fluorenylene unit, as a building block for conjugated systems. This research has elucidated novel chromophores and polymers and explored their properties so as to better understand the influence of sterics on photophysical behavior within conjugated systems, while also improving and devising new methods to be able to synthesize chromophores and polymers that can be tuned to exhibit certain photophysical or electrochemical behavior.
520 $a A general overview of why conjugated materials are useful in optoelectronics, different type of conjugated materials, and some targeted applications is presented in Chapter 1. A more detailed study of polymers built on a 1,4-fluorenylene unit is presented in Chapters 2 and 3, while Chapter 4 explores the development of a new polymerization route for PPVs to reduce incidence of defects in the final polymer. Chapters 5 -- 7 include a detailed investigation of 1,4-fluorenylene-containing chromophores. Chapter 5 focuses on symmetrically substituted 1,4-fluorenylenes, while Chapter 7 describes the synthesis and characterization of asymmetrically substituted 1,4-fluorenylene units. Chapter 6 demonstrates a new method for asymmetrically substituting aromatic compounds using species that contain phosphonate and phosphonium groups.
590 $a School code: 0050.
650 4 $a Chemistry, General. $3 1021807
650 4 $a Chemistry, Polymer. $3 1018428
650 4 $a Chemistry, Physical. $3 560527
690 $a 0485
690 $a 0495
690 $a 0494
710 2 $a Clemson University. $b Chemistry. $3 1030764
773 0 $t Dissertation Abstracts International $g 74-10B(E).
790 $a 0050
791 $a Ph.D.
792 $a 2013
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3565115