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Smart nickel oxide materials for the...

Lin, Feng.

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Smart nickel oxide materials for the applications of energy efficiency and storage.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Smart nickel oxide materials for the applications of energy efficiency and storage./
Author:	Lin, Feng.
Description:	152 p.
Notes:	Source: Dissertation Abstracts International, Volume: 74-04(E), Section: B.
Contained By:	Dissertation Abstracts International74-04B(E).
Subject:	Engineering, Materials Science. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3545482
ISBN:	9781267778130

Smart nickel oxide materials for the applications of energy efficiency and storage.
Lin, Feng.

Smart nickel oxide materials for the applications of energy efficiency and storage. - 152 p.

Source: Dissertation Abstracts International, Volume: 74-04(E), Section: B.

Thesis (Ph.D.)--Colorado School of Mines, 2012.

The present dissertation studies nickel oxide-based materials for the application of electrochromic windows and lithium-air batteries. The materials were fabricated via radio frequency magnetron sputtering and subsequently post-treated with thermal evaporation and ozone exposure. The strategies to improve electrochromic performance of nickel oxide materials were investigated including compositional control, morphology tuning, modification of electronic structure and interface engineering (i.e., Li2O 2, graphene). The electrochemical properties of the resulting materials were characterized in lithium ion electrolytes. Extremely high performing nickel oxide-based electrochromic materials were obtained in terms of optical modulation, switching kinetics, bleached-state transparency and durability, which promise the implementation of these materials for practical smart windows. With the aid of advanced synchrotron X-ray absorption spectroscopy, it is reported for the first time that the electrochromic effect in multicomponent nickel oxide-based materials arises from the reversible formation of hole states in the NiO6 cluster accompanying with the reversible formation of Li2O2. The reversible formation of Li2O 2 was successfully leveraged with the study of electro-catalysts and cathode materials for lithium-air batteries. The reversibility of Li 2O2 was thoroughly investigated using soft X-ray absorption spectroscopy and theoretical simulation, which substantiates the promise of using electrochromic films as electro-catalysts and/or cathode materials in lithium-air batteries.

ISBN: 9781267778130Subjects--Topical Terms:

1017759
Engineering, Materials Science.

Smart nickel oxide materials for the applications of energy efficiency and storage.
LDR:02498nam a2200277 4500 001 1958461
005 20140421080357.5
008 150210s2012 ||||||||||||||||| ||eng d
020 $a 9781267778130
035 $a (MiAaPQ)AAI3545482
035 $a AAI3545482
040 $a MiAaPQ $c MiAaPQ
100 1 $a Lin, Feng. $3 1941451
245 1 0 $a Smart nickel oxide materials for the applications of energy efficiency and storage.
300 $a 152 p.
500 $a Source: Dissertation Abstracts International, Volume: 74-04(E), Section: B.
500 $a Advisers: Ryan M. Richards; Chaiwat Engtrakul.
502 $a Thesis (Ph.D.)--Colorado School of Mines, 2012.
520 $a The present dissertation studies nickel oxide-based materials for the application of electrochromic windows and lithium-air batteries. The materials were fabricated via radio frequency magnetron sputtering and subsequently post-treated with thermal evaporation and ozone exposure. The strategies to improve electrochromic performance of nickel oxide materials were investigated including compositional control, morphology tuning, modification of electronic structure and interface engineering (i.e., Li2O 2, graphene). The electrochemical properties of the resulting materials were characterized in lithium ion electrolytes. Extremely high performing nickel oxide-based electrochromic materials were obtained in terms of optical modulation, switching kinetics, bleached-state transparency and durability, which promise the implementation of these materials for practical smart windows. With the aid of advanced synchrotron X-ray absorption spectroscopy, it is reported for the first time that the electrochromic effect in multicomponent nickel oxide-based materials arises from the reversible formation of hole states in the NiO6 cluster accompanying with the reversible formation of Li2O2. The reversible formation of Li2O 2 was successfully leveraged with the study of electro-catalysts and cathode materials for lithium-air batteries. The reversibility of Li 2O2 was thoroughly investigated using soft X-ray absorption spectroscopy and theoretical simulation, which substantiates the promise of using electrochromic films as electro-catalysts and/or cathode materials in lithium-air batteries.
590 $a School code: 0052.
650 4 $a Engineering, Materials Science. $3 1017759
650 4 $a Chemistry, Inorganic. $3 517253
690 $a 0794
690 $a 0488
710 2 $a Colorado School of Mines. $b Chemistry and Geochemistry. $3 2093552
773 0 $t Dissertation Abstracts International $g 74-04B(E).
790 $a 0052
791 $a Ph.D.
792 $a 2012
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3545482