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Production of glycerol-free biofuel ...

Islam, Mohammad Rafiqul.

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Production of glycerol-free biofuel from canola oil and dimethyl carbonate using triazabicyclodecene in homogeneous and heterogeneous catalysis operations.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Production of glycerol-free biofuel from canola oil and dimethyl carbonate using triazabicyclodecene in homogeneous and heterogeneous catalysis operations./
作者:	Islam, Mohammad Rafiqul.
面頁冊數:	195 p.
附註:	Source: Dissertation Abstracts International, Volume: 74-09(E), Section: B.
Contained By:	Dissertation Abstracts International74-09B(E).
標題:	Alternative Energy. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3562300
ISBN:	9781303098772

Production of glycerol-free biofuel from canola oil and dimethyl carbonate using triazabicyclodecene in homogeneous and heterogeneous catalysis operations.
Islam, Mohammad Rafiqul.

Production of glycerol-free biofuel from canola oil and dimethyl carbonate using triazabicyclodecene in homogeneous and heterogeneous catalysis operations. - 195 p.

Source: Dissertation Abstracts International, Volume: 74-09(E), Section: B.

Thesis (Ph.D.)--Lamar University - Beaumont, 2013.

Due to the increasing awareness of the dwindling fossil fuel resources and environmental issues, biofuel became an alternative renewable fuel to meet the steady increase of energy consumption and environmental demands. This work was designed to produce biofuel free from glycerol, soap, catalyst and wastes from canola oil and dimethyl carbonate (DMC) using an organocatalyst, triazabicyclodecene (TBD). To achieve these goals, several interconnected research activities were undertaken. First, a flow sheet was developed for the process and operating criteria were identified by laboratory experimentation verified with Aspen Plus. Mass and energy integration studies were performed to minimize the consumption of materials and energy utilities. Next, kinetics of canola oil transesterification using TBD as homogeneous catalyst in dimethyl carbonate has been investigated and a model was developed. Kinetics data were vital in process assessment and kinetics model was essential in the study of chemical reaction and catalyst development. Finally, a heterogeneous catalyst was developed for use as a biofuel catalyst through the immobilization of TBD into MgAl layered double hydroxides (LDHs) which can combine the advantages of homogeneous catalysis with the best properties of heterogeneous materials.

ISBN: 9781303098772Subjects--Topical Terms:

1035473
Alternative Energy.

Production of glycerol-free biofuel from canola oil and dimethyl carbonate using triazabicyclodecene in homogeneous and heterogeneous catalysis operations.
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