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The functionalization of metallic an...

Schmeltzer, Jason M.

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The functionalization of metallic and semiconductor surfaces with organic and inorganic species.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	The functionalization of metallic and semiconductor surfaces with organic and inorganic species./
作者:	Schmeltzer, Jason M.
面頁冊數:	166 p.
附註:	Source: Dissertation Abstracts International, Volume: 64-11, Section: B, page: 5519.
Contained By:	Dissertation Abstracts International64-11B.
標題:	Chemistry, Inorganic. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3113868

The functionalization of metallic and semiconductor surfaces with organic and inorganic species.
Schmeltzer, Jason M.

The functionalization of metallic and semiconductor surfaces with organic and inorganic species. - 166 p.

Source: Dissertation Abstracts International, Volume: 64-11, Section: B, page: 5519.

Thesis (Ph.D.)--Purdue University, 2003.

The discipline of surface chemistry has rapidly expanded within recent years, attaining richness and diversity not unlike the more traditional divisions of organic, inorganic, physical, and biological chemistries. The boundless human drive to better understand the natural order as well as to better improve the existence of mankind has not ignored the physical, material, and chemical activities of interfaces, but rather the opposite. As computers shrink to ever-smaller sizes while growing in complexity---as devices and machines diminish to near-inconceivable dimensions---as the agents of technology miniaturize to comply with the endless demands of more-for-less---the chemistry of surfaces will continue to fulfill a crucial part in the advancement of new industries.Subjects--Topical Terms:

517253
Chemistry, Inorganic.

The functionalization of metallic and semiconductor surfaces with organic and inorganic species.
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245 1 4 $a The functionalization of metallic and semiconductor surfaces with organic and inorganic species.
300 $a 166 p.
500 $a Source: Dissertation Abstracts International, Volume: 64-11, Section: B, page: 5519.
500 $a Major Professor: Jillian M. Buriak.
502 $a Thesis (Ph.D.)--Purdue University, 2003.
520 $a The discipline of surface chemistry has rapidly expanded within recent years, attaining richness and diversity not unlike the more traditional divisions of organic, inorganic, physical, and biological chemistries. The boundless human drive to better understand the natural order as well as to better improve the existence of mankind has not ignored the physical, material, and chemical activities of interfaces, but rather the opposite. As computers shrink to ever-smaller sizes while growing in complexity---as devices and machines diminish to near-inconceivable dimensions---as the agents of technology miniaturize to comply with the endless demands of more-for-less---the chemistry of surfaces will continue to fulfill a crucial part in the advancement of new industries.
520 $a This thesis details work into three realms of surface chemistry. Chapter One introduces porous silicon and presents a background of this unique, nanocrystalline substance. Described particularly is a new surface reaction to functionalize this material with organic groups; named carbocation-mediated hydrosilylation, this chemical treatment yields substrates derivatized with silicon-carbon bonds, the optimal surface group for imparting stability and functionality to the easily corroded, chemically limited material. Chapter Two discusses the electroless deposition of noble metal particles upon a number of metal and semiconductor surfaces. These reactions require neither external reducing agents nor electrical current to accomplish the formation of metal films, exciting and essential not merely from the fundamental perspectives of surface researches, but also from the aspects of fabricating micro- and nanoscale devices via controlled and patterned metallization reactions. Chapter Three returns to porous silicon and discusses attempts to covalently functionalize the material surface with thiolate-encapsulated gold nanoparticles; such surface-bound species may be useful for sensing, composite materials, and a myriad of other utilities.
590 $a School code: 0183.
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