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Novel poly(benzyl ether) and poly(be...

Freeman, Adam Wade.

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Novel poly(benzyl ether) and poly(benzyl ester) dendrimers: Syntheses and applications.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Novel poly(benzyl ether) and poly(benzyl ester) dendrimers: Syntheses and applications./
Author:	Freeman, Adam Wade.
Description:	122 p.
Notes:	Source: Dissertation Abstracts International, Volume: 61-07, Section: B, page: 3594.
Contained By:	Dissertation Abstracts International61-07B.
Subject:	Chemistry, Organic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=9979625
ISBN:	0599859059

Novel poly(benzyl ether) and poly(benzyl ester) dendrimers: Syntheses and applications.
Freeman, Adam Wade.

Novel poly(benzyl ether) and poly(benzyl ester) dendrimers: Syntheses and applications. - 122 p.

Source: Dissertation Abstracts International, Volume: 61-07, Section: B, page: 3594.

Thesis (Ph.D.)--University of California, Berkeley, 2000.

Over the past two decades, dendritic macromolecules have captured the attention of the scientific community due to their unique architectures and concomitant materials properties as compared to their linear analogs. With the continued maturation of this field, comes constant vacillation between exploring new applications for existing dendritic systems, and the development of “improved” synthetic methods to make these macromolecules more efficiently, in anticipation of the next wave of potential applications, or for the much more elusive goal of widespread commercialization. This dissertation addresses several recent advances in the preparation of poly(benzyl ether) and poly(benzyl ester) dendrimers and some of the applications they aspire to fulfill.

ISBN: 0599859059Subjects--Topical Terms:

516206
Chemistry, Organic.

Novel poly(benzyl ether) and poly(benzyl ester) dendrimers: Syntheses and applications.
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100 1 $a Freeman, Adam Wade. $3 1945817
245 1 0 $a Novel poly(benzyl ether) and poly(benzyl ester) dendrimers: Syntheses and applications.
300 $a 122 p.
500 $a Source: Dissertation Abstracts International, Volume: 61-07, Section: B, page: 3594.
500 $a Adviser: Jean M. J. Frechet.
502 $a Thesis (Ph.D.)--University of California, Berkeley, 2000.
520 $a Over the past two decades, dendritic macromolecules have captured the attention of the scientific community due to their unique architectures and concomitant materials properties as compared to their linear analogs. With the continued maturation of this field, comes constant vacillation between exploring new applications for existing dendritic systems, and the development of “improved” synthetic methods to make these macromolecules more efficiently, in anticipation of the next wave of potential applications, or for the much more elusive goal of widespread commercialization. This dissertation addresses several recent advances in the preparation of poly(benzyl ether) and poly(benzyl ester) dendrimers and some of the applications they aspire to fulfill.
520 $a Chapter 2 describes a fundamental study of the ability of convergently prepared poly(benzyl ether) monodendrons to self-assemble into <italic>dendrimers </italic> based upon the putative hexameric hydrogen bonded rosette substructure of the cyanuric acid-melamine (CA-M) lattice.
520 $a Chapter 3 describes the accelerated preparation of a novel family of structurally-homogenous poly(benzyl ester) dendrimers using a new orthogonal monomer approach. These dendrimers, which are synthesized at the rate of one generation per reaction and in high yields, show promise in applications were the need for dendrimer size outweighs the need for structural robustness.
520 $a Chapter 4 describes the first method for creating controlled diversity within dendritic structures. This new approach combines the synthetically powerful techniques of double-stage convergent growth and parallel synthesis to generate <italic>series</italic> of large poly (benzyl ether) dendrimers quickly and with precise control over functional group placement throughout the macromolecule.
520 $a Chapter 5 describes a novel family of chromophore-labeled poly(benzyl ether) dendrimers and their use in single-layer organic light-emitting diodes (OLED). Within these macromolecules, energy (both photochemical and electrochemical) is harvested at the periphery and efficiently funneled to the luminescent core that produces the observed light. In addition to devices formulated with a single type of dendrimer, devices containing multiple types of dendrimers with different chromaticities are described as a new approach toward color tunable, single-layer OLEDs.
590 $a School code: 0028.
650 4 $a Chemistry, Organic. $3 516206
650 4 $a Chemistry, Polymer. $3 1018428
690 $a 0490
690 $a 0495
710 2 0 $a University of California, Berkeley. $3 687832
773 0 $t Dissertation Abstracts International $g 61-07B.
790 1 0 $a Frechet, Jean M. J., $e advisor
790 $a 0028
791 $a Ph.D.
792 $a 2000
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=9979625