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Synthetic routes and applications of...
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Jiang, Ping.
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Synthetic routes and applications of photonic crystal composites.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Synthetic routes and applications of photonic crystal composites./
作者:
Jiang, Ping.
面頁冊數:
209 p.
附註:
Source: Dissertation Abstracts International, Volume: 65-08, Section: B, page: 4048.
Contained By:
Dissertation Abstracts International65-08B.
標題:
Chemistry, Polymer. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3142973
ISBN:
0496009060
Synthetic routes and applications of photonic crystal composites.
Jiang, Ping.
Synthetic routes and applications of photonic crystal composites.
- 209 p.
Source: Dissertation Abstracts International, Volume: 65-08, Section: B, page: 4048.
Thesis (Ph.D.)--Clemson University, 2004.
This dissertation focuses on: (1) the development of synthetic routes to fabricate robust photonic crystal composites that allows for a wide range of monomeric systems to be utilized in the encapsulation procedure to a priori design the final optical and thermomechanical characteristics of the composite and (2) the characterization of the optical and thermomechanical properties of the composites and their exploitation in potential applications.
ISBN: 0496009060Subjects--Topical Terms:
1018428
Chemistry, Polymer.
Synthetic routes and applications of photonic crystal composites.
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In the first section, two strategies were developed, one using poly(ethylene glycol) (PEG) and its acrylate derivatives as matrixes to encapsulate the CCA of polystyrene spheres and to form a photonic crystal hydrogel (PCH) composite. The second strategy employs the technique of first dehydrating the PCH composite, then swelling it in a monomeric solution, and finally photopolymerizing it in situ, to form a water-free photonic crystal, or photonic band gap (PBG) composite.
520
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In the second section, the mechanochromic and solvatochromic responses of the PBG composite composed of poly(EGMEA) were characterized. This composite exhibited a reversible color variation at deformation frequencies up to 200 Hz and a 172 nm total stop band tuning range between +/-120V applied voltages when it was coupled with a piezoelectric actuator. Based on this effect, approaches for generating complex permanent multicolor patterns in both PBG and PCH films were developed.
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Finally, two types of potential sensing systems were explored in this dissertation. One is a chemical vapor sensing system composed of the poly(EGMEA)-based PBG composite film. The second is a label-free optical bio-recognition system composed of an antigen-selective photonic crystal hydrogel (PCH). The avidin molecules were first covalently immobilized in the PCH film. The biotinylated capture antibody was then introduced into the film through the non-covalent avidin-biotin binding. (Abstract shortened by UMI.)
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