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Microwave assisted Diels-Alder react...
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Obot, Emmanuel Okon.
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Microwave assisted Diels-Alder reaction: Synthesis of substituted furan, pyridine and benzene.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Microwave assisted Diels-Alder reaction: Synthesis of substituted furan, pyridine and benzene./
作者:
Obot, Emmanuel Okon.
面頁冊數:
52 p.
附註:
Source: Masters Abstracts International, Volume: 42-06, page: 2210.
Contained By:
Masters Abstracts International42-06.
標題:
Chemistry, Organic. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1420573
ISBN:
0496253220
Microwave assisted Diels-Alder reaction: Synthesis of substituted furan, pyridine and benzene.
Obot, Emmanuel Okon.
Microwave assisted Diels-Alder reaction: Synthesis of substituted furan, pyridine and benzene.
- 52 p.
Source: Masters Abstracts International, Volume: 42-06, page: 2210.
Thesis (M.S.)--Morgan State University, 2004.
Microwave assisted synthesis is affecting the field of organic chemistry greatly. Reactions under the microwaves tend to go faster. The reactions are fast and high yielding, and do not need of supporting solvents. Microwave assisted reactions are increasing exponentially and it being used in industry, and academic labs. In this instance, there is a focus on the Diels-Alder (DA) reactions under microwaves as this reaction is a thermal reaction and is a good candidate for study under microwaves.
ISBN: 0496253220Subjects--Topical Terms:
516206
Chemistry, Organic.
Microwave assisted Diels-Alder reaction: Synthesis of substituted furan, pyridine and benzene.
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Source: Masters Abstracts International, Volume: 42-06, page: 2210.
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Adviser: Yousef Hijji.
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Thesis (M.S.)--Morgan State University, 2004.
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Microwave assisted synthesis is affecting the field of organic chemistry greatly. Reactions under the microwaves tend to go faster. The reactions are fast and high yielding, and do not need of supporting solvents. Microwave assisted reactions are increasing exponentially and it being used in industry, and academic labs. In this instance, there is a focus on the Diels-Alder (DA) reactions under microwaves as this reaction is a thermal reaction and is a good candidate for study under microwaves.
520
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This work presents microwave assisted DA reactions of the dienes, 2,5-dimethylfuran and 2,4,5-trimethyloxazole, 2-trimethylsilyloxy1,3-cyclohexadienes and 2-butyl-1,3-cyclohexadienes with acetylenic and olefinic dienophiles. Microwave assisted reactions were run from 2 to 20 minutes. The DA reactions of the dienes with acetylenic dienophile resulted in the formation of the cycloadduct as an intermediate that proceeded via the retro DA reaction to give substituted furan, pyridine and substituted benzene in good yields 60--90%. (Abstract shortened by UMI.)
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http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1420573
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