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Synthesis and reactivity of palladiu...

Culkin, Darcy Ann.

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Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides./
作者:	Culkin, Darcy Ann.
面頁冊數:	285 p.
附註:	Source: Dissertation Abstracts International, Volume: 65-03, Section: B, page: 1316.
Contained By:	Dissertation Abstracts International65-03B.
標題:	Chemistry, Inorganic. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3125179
ISBN:	049672469X

Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides.
Culkin, Darcy Ann.

Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides. - 285 p.

Source: Dissertation Abstracts International, Volume: 65-03, Section: B, page: 1316.

Thesis (Ph.D.)--Yale University, 2004.

A series of arylpalladium alkyl complexes containing varied functional groups alpha to the metal was prepared to reveal the effect of ligand steric and electronic properties on structure, stability, and reactivity. Arylpalladium complexes of methyl, benzyl, enolate, cyanoalkyl, and trifluoroethyl groups underwent carbon-carbon bond-forming reductive elimination upon heating. Mechanistic studies of the reductive elimination process led to the discovery of a new coupling reaction, the palladium-catalyzed alpha-arylation of nitriles, and to the development of improved methods for the palladium-catalyzed synthesis of alpha-aryl amides.

ISBN: 049672469XSubjects--Topical Terms:

517253
Chemistry, Inorganic.

Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides.
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520 $a A series of arylpalladium alkyl complexes containing varied functional groups alpha to the metal was prepared to reveal the effect of ligand steric and electronic properties on structure, stability, and reactivity. Arylpalladium complexes of methyl, benzyl, enolate, cyanoalkyl, and trifluoroethyl groups underwent carbon-carbon bond-forming reductive elimination upon heating. Mechanistic studies of the reductive elimination process led to the discovery of a new coupling reaction, the palladium-catalyzed alpha-arylation of nitriles, and to the development of improved methods for the palladium-catalyzed synthesis of alpha-aryl amides.
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