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Controlling the work function of ind...

Bruner, Eric Lawrence.

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Controlling the work function of indium tin oxide with organometallic surface complexes.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Controlling the work function of indium tin oxide with organometallic surface complexes./
Author:	Bruner, Eric Lawrence.
Description:	128 p.
Notes:	Source: Dissertation Abstracts International, Volume: 63-10, Section: B, page: 4645.
Contained By:	Dissertation Abstracts International63-10B.
Subject:	Chemistry, General. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3068785
ISBN:	0493884319

Controlling the work function of indium tin oxide with organometallic surface complexes.
Bruner, Eric Lawrence.

Controlling the work function of indium tin oxide with organometallic surface complexes. - 128 p.

Source: Dissertation Abstracts International, Volume: 63-10, Section: B, page: 4645.

Thesis (Ph.D.)--Princeton University, 2003.

The reactions of tetra(tert-butoxy)tin and tetrakis(diethylamino)tin with indium in oxide (ITO) give surface-bound tin alkoxide and tin amide complexes respectively. Organic acids with appropriate acidities initiate ligand metathesis with these surface complexes. Surface bound (arylacetylide)tin and (phenoxide)tin species were synthesized in ultra-high vacuum and characterized by X-ray photoelectron spectroscopy, mass spectrometry, and reflective absorption infrared spectroscopy. A series of substituted phenols, with a range of dipole moments and acidities, was reacted with surface-bound tin alkoxide to probe the validity of a dipole-moment model. The use of o- and p-substituted phenoxytin surface complexes demonstrated that dipolar properties of the surface bound species, and not local electronegativity effects, control the work function of ITO.

ISBN: 0493884319Subjects--Topical Terms:

1021807
Chemistry, General.

Controlling the work function of indium tin oxide with organometallic surface complexes.
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040 $a UnM $c UnM
100 1 $a Bruner, Eric Lawrence. $3 1931839
245 1 0 $a Controlling the work function of indium tin oxide with organometallic surface complexes.
300 $a 128 p.
500 $a Source: Dissertation Abstracts International, Volume: 63-10, Section: B, page: 4645.
502 $a Thesis (Ph.D.)--Princeton University, 2003.
520 $a The reactions of tetra(tert-butoxy)tin and tetrakis(diethylamino)tin with indium in oxide (ITO) give surface-bound tin alkoxide and tin amide complexes respectively. Organic acids with appropriate acidities initiate ligand metathesis with these surface complexes. Surface bound (arylacetylide)tin and (phenoxide)tin species were synthesized in ultra-high vacuum and characterized by X-ray photoelectron spectroscopy, mass spectrometry, and reflective absorption infrared spectroscopy. A series of substituted phenols, with a range of dipole moments and acidities, was reacted with surface-bound tin alkoxide to probe the validity of a dipole-moment model. The use of o- and p-substituted phenoxytin surface complexes demonstrated that dipolar properties of the surface bound species, and not local electronegativity effects, control the work function of ITO.
590 $a School code: 0181.
650 4 $a Chemistry, General. $3 1021807
690 $a 0485
710 2 0 $a Princeton University. $3 645579
773 0 $t Dissertation Abstracts International $g 63-10B.
790 $a 0181
791 $a Ph.D.
792 $a 2003
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3068785