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Symmetries and relaxations in non-eq...

DeSimone, Anthony Joseph, Jr.

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Symmetries and relaxations in non-equilibrium thermodynamics.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Symmetries and relaxations in non-equilibrium thermodynamics./
作者:	DeSimone, Anthony Joseph, Jr.
面頁冊數:	131 p.
附註:	Source: Dissertation Abstracts International, Volume: 66-03, Section: B, page: 1509.
Contained By:	Dissertation Abstracts International66-03B.
標題:	Physics, General. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3167566
ISBN:	9780542032141

Symmetries and relaxations in non-equilibrium thermodynamics.
DeSimone, Anthony Joseph, Jr.

Symmetries and relaxations in non-equilibrium thermodynamics. - 131 p.

Source: Dissertation Abstracts International, Volume: 66-03, Section: B, page: 1509.

Thesis (Ph.D.)--Drexel University, 2005.

Static thermodynamic susceptibilities obey symmetries that have been known for a very long time. These are the Maxwell relations. Less well-known are the symmetry properties that are consequences of a certain type of perturbation. These are the Le Chatelier reciprocal relations. These involve relaxation of thermodynamic extensive and intensive parameters to new static equilibrium values after a sudden perturbation. Since time-dependent thermodynamic properties are governed by the fundamental equations of nonequilibrium thermodynamics, we expect the time constants of these relaxations to be governed, to some extent, by Onsager's kinetic coefficients. In this work we address the time scales and symmetries of these relaxation processes which have not been previously addressed. We explore the relation between the static susceptibilities (Maxwell relations) of equilibrium thermodynamics, the symmetries of the Le Chatelier reciprocal relations, as contained in the Le Chatelier matrix, the symmetries of the kinetic coefficients, which govern the relaxation dynamics of nonequilibrium processes, and the symmetries of the Fluctuation-Dissipation theorem.

ISBN: 9780542032141Subjects--Topical Terms:

1018488
Physics, General.

Symmetries and relaxations in non-equilibrium thermodynamics.
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520 $a Static thermodynamic susceptibilities obey symmetries that have been known for a very long time. These are the Maxwell relations. Less well-known are the symmetry properties that are consequences of a certain type of perturbation. These are the Le Chatelier reciprocal relations. These involve relaxation of thermodynamic extensive and intensive parameters to new static equilibrium values after a sudden perturbation. Since time-dependent thermodynamic properties are governed by the fundamental equations of nonequilibrium thermodynamics, we expect the time constants of these relaxations to be governed, to some extent, by Onsager's kinetic coefficients. In this work we address the time scales and symmetries of these relaxation processes which have not been previously addressed. We explore the relation between the static susceptibilities (Maxwell relations) of equilibrium thermodynamics, the symmetries of the Le Chatelier reciprocal relations, as contained in the Le Chatelier matrix, the symmetries of the kinetic coefficients, which govern the relaxation dynamics of nonequilibrium processes, and the symmetries of the Fluctuation-Dissipation theorem.
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