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Design and syntheses of polymeric ma...

Clancy, Sean Owen.

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Design and syntheses of polymeric materials for visible and near-infrared emitting applications.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Design and syntheses of polymeric materials for visible and near-infrared emitting applications./
作者:	Clancy, Sean Owen.
面頁冊數:	182 p.
附註:	Source: Dissertation Abstracts International, Volume: 66-06, Section: B, page: 3133.
Contained By:	Dissertation Abstracts International66-06B.
標題:	Chemistry, Organic. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3180416
ISBN:	9780542205125

Design and syntheses of polymeric materials for visible and near-infrared emitting applications.
Clancy, Sean Owen.

Design and syntheses of polymeric materials for visible and near-infrared emitting applications. - 182 p.

Source: Dissertation Abstracts International, Volume: 66-06, Section: B, page: 3133.

Thesis (Ph.D.)--University of Southern California, 2005.

Several classes of polyphenylene-type polymeric materials were synthesized according to several different design parameters, with the end results of each being able to sensitize small molecule organics or lanthanide chelates as dopants which emit energy in the visible and/or near-infrared regions of the electromagnetic spectrum. The goal of this research was to create materials that would emit in the near-infrared. The first group of materials was para-para linked polyphenylene-type polymers doped with several small molecule organic dyes. The second group was para-para and para-meta linked polyphenylene-type polymers doped with a series of Coumarins and a couple metalloporphines. The third group was para-meta linked polyphenylene-type polymers with pendant terpyridine groups. The fourth group was para-meta linked polyphenylene-type polymers with various pendant beta-diketonates to which europium complexes were bound. The fifth group was para-meta linked polyphenylene-type polymers with various pendant beta-diketonates to which erbium-porphyrinate complexes were bound.

ISBN: 9780542205125Subjects--Topical Terms:

516206
Chemistry, Organic.

Design and syntheses of polymeric materials for visible and near-infrared emitting applications.
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520 $a Several classes of polyphenylene-type polymeric materials were synthesized according to several different design parameters, with the end results of each being able to sensitize small molecule organics or lanthanide chelates as dopants which emit energy in the visible and/or near-infrared regions of the electromagnetic spectrum. The goal of this research was to create materials that would emit in the near-infrared. The first group of materials was para-para linked polyphenylene-type polymers doped with several small molecule organic dyes. The second group was para-para and para-meta linked polyphenylene-type polymers doped with a series of Coumarins and a couple metalloporphines. The third group was para-meta linked polyphenylene-type polymers with pendant terpyridine groups. The fourth group was para-meta linked polyphenylene-type polymers with various pendant beta-diketonates to which europium complexes were bound. The fifth group was para-meta linked polyphenylene-type polymers with various pendant beta-diketonates to which erbium-porphyrinate complexes were bound.
520 $a The first and second groups served as preliminary studies on the energy transfer properties of polymers to organic dyes. With a better understanding of how doped conjugated polymers behaved, other polymers were designed with specific structural properties that lead to the desired photophysical properties. This elaboration of structure-property relationships also lead to the pendant groups to which the lanthanides would be datively or covalently bonded to the polymer, as was studied with the third and fourth groups, respectively. Upon this foundation, the fifth group of materials reached the goal of having polymeric-materials that emitted energy in the near-infrared region of the electromagnetic spectrum.
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