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Thermodynamics of diffusion.

Matuszak, Daniel.

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Thermodynamics of diffusion.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Thermodynamics of diffusion./
Author:	Matuszak, Daniel.
Description:	246 p.
Notes:	Source: Dissertation Abstracts International, Volume: 66-12, Section: B, page: 6774.
Contained By:	Dissertation Abstracts International66-12B.
Subject:	Engineering, Chemical. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3197201
ISBN:	9780542430305

Thermodynamics of diffusion.
Matuszak, Daniel.

Thermodynamics of diffusion. - 246 p.

Source: Dissertation Abstracts International, Volume: 66-12, Section: B, page: 6774.

Thesis (Ph.D.)--The Johns Hopkins University, 2006.

Diffusion is the migration of molecules in the reference frame of a system's center of mass and it is a physical process that occurs in all chemical and biological systems. Diffusion generally involves intermolecular interactions that lead to clustering, adsorption, and phase transitions; as such, it is difficult to describe theoretically on a molecular level in systems containing both intermolecular repulsions and attractions.

ISBN: 9780542430305Subjects--Topical Terms:

1018531
Engineering, Chemical.

Thermodynamics of diffusion.
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100 1 $a Matuszak, Daniel. $3 1913976
245 1 0 $a Thermodynamics of diffusion.
300 $a 246 p.
500 $a Source: Dissertation Abstracts International, Volume: 66-12, Section: B, page: 6774.
500 $a Adviser: Marc D. Donohue.
502 $a Thesis (Ph.D.)--The Johns Hopkins University, 2006.
520 $a Diffusion is the migration of molecules in the reference frame of a system's center of mass and it is a physical process that occurs in all chemical and biological systems. Diffusion generally involves intermolecular interactions that lead to clustering, adsorption, and phase transitions; as such, it is difficult to describe theoretically on a molecular level in systems containing both intermolecular repulsions and attractions.
520 $a This work describes a simple thermodynamic approach that accounts for intermolecular attractions and repulsions (much like how the van der Waals equation does) to model and help provide an understanding of diffusion. The approach is an extension of the equilibrium Lattice Density Functional Theory of Aranovich and Donohue; it was developed with Mason and Lonsdale's guidelines on how to construct and test a transport theory.
520 $a In the framework of lattice fluids, this new approach gives (a) correct equilibrium limits, (b) Fickian behavior for non-interacting systems, (c) correct departures from Fickian behavior in non-ideal systems, (d) the correct Maxwell-Stefan formulation, (e) symmetry behavior upon re-labeling species, (f) reasonable non-equilibrium phase behavior, (g) agreement with Molecular Dynamics simulations, (h) agreement with the theory of non-equilibrium thermodynamics, (i) a vanishing diffusive flux at the critical point, and (j) other qualitatively-correct behaviors when applied to problems in porous membranes and in packed beds.
590 $a School code: 0098.
650 4 $a Engineering, Chemical. $3 1018531
650 4 $a Chemistry, Physical. $3 560527
650 4 $a Physics, Molecular. $3 1018648
690 $a 0542
690 $a 0494
690 $a 0609
710 2 0 $a The Johns Hopkins University. $3 1017431
773 0 $t Dissertation Abstracts International $g 66-12B.
790 1 0 $a Donohue, Marc D., $e advisor
790 $a 0098
791 $a Ph.D.
792 $a 2006
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3197201