東華大學圖書館 |

語系: 繁體中文

說明(常見問題)

回圖書館首頁

手機版館藏查詢

登入

回首頁

切換: 標籤 | MARC模式 | ISBD

FindBook

Google Book

Amazon

博客來

Palladium-Catalyzed Cross-Coupling and Related Reactions of Non-Classical Electrophiles Focusing on Esters.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Palladium-Catalyzed Cross-Coupling and Related Reactions of Non-Classical Electrophiles Focusing on Esters./
作者:	Dardir, Amira H.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, : 2021,
面頁冊數:	376 p.
附註:	Source: Dissertations Abstracts International, Volume: 83-02, Section: B.
Contained By:	Dissertations Abstracts International83-02B.
標題:	Chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28258148
ISBN:	9798534650006

Palladium-Catalyzed Cross-Coupling and Related Reactions of Non-Classical Electrophiles Focusing on Esters.
Dardir, Amira H.

Palladium-Catalyzed Cross-Coupling and Related Reactions of Non-Classical Electrophiles Focusing on Esters. - Ann Arbor : ProQuest Dissertations & Theses, 2021 - 376 p.

Source: Dissertations Abstracts International, Volume: 83-02, Section: B.

Thesis (Ph.D.)--Yale University, 2021.

This item must not be sold to any third party vendors.

This thesis summarizes work related to the development of mild palladium-catalyzed cross-coupling reactions of phenyl- and benzyl- esters, which undergo different C-O bond cleavage selectivity, the scope of the reactions and applications, and mechanistic understanding of precatalyst activation and the oxidative addition steps. The first chapter of this thesis is an introduction summarizing palladium-catalyzed cross-coupling reactions of non-classical electrophiles. The second chapter focus on the development of mild palladium-catalyzed non- decarbonylative Suzuk-Miyuara and Buchwald Hartwig cross-coupling reactions of phenyl aryl- and alkyl-esters to generate ketenes and amides, respectively. The third chapter is the extension of the Suzuki-Miyuara reactions to phenyl ester derivatives of aspartic acid to synthesize aryl amino ketones. Chapter four describes the development of mild palladium-catalyzed Suzuki-Miyuara reactions of diaryl methyl 2,3,4,5,6-pentafluorobenzoates to synthesize triarylmethanes.The first appendix describes preliminary work on palladium-catalyzed benzylic decarboxylation reactions as a more atom economical method for the synthesis of diarylmethanes. The second appendix describes preliminary work on palladium-catalyzed Suzuki-Miyaura reactions of activated aziridines and stoichiometric reactions of phosphine ligated nickel complexes with activated aziridines.

ISBN: 9798534650006Subjects--Topical Terms:

516420
Chemistry.
Subjects--Index Terms:

Cross-coupling reactions

Palladium-Catalyzed Cross-Coupling and Related Reactions of Non-Classical Electrophiles Focusing on Esters.
LDR:02525nmm a2200337 4500 001 2352308
005 20221128103617.5
008 241004s2021 ||||||||||||||||| ||eng d
020 $a 9798534650006
035 $a (MiAaPQ)AAI28258148
035 $a AAI28258148
040 $a MiAaPQ $c MiAaPQ
100 1 $a Dardir, Amira H. $3 3691926
245 1 0 $a Palladium-Catalyzed Cross-Coupling and Related Reactions of Non-Classical Electrophiles Focusing on Esters.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2021
300 $a 376 p.
500 $a Source: Dissertations Abstracts International, Volume: 83-02, Section: B.
500 $a Advisor: Hazari, Nilay.
502 $a Thesis (Ph.D.)--Yale University, 2021.
506 $a This item must not be sold to any third party vendors.
520 $a This thesis summarizes work related to the development of mild palladium-catalyzed cross-coupling reactions of phenyl- and benzyl- esters, which undergo different C-O bond cleavage selectivity, the scope of the reactions and applications, and mechanistic understanding of precatalyst activation and the oxidative addition steps. The first chapter of this thesis is an introduction summarizing palladium-catalyzed cross-coupling reactions of non-classical electrophiles. The second chapter focus on the development of mild palladium-catalyzed non- decarbonylative Suzuk-Miyuara and Buchwald Hartwig cross-coupling reactions of phenyl aryl- and alkyl-esters to generate ketenes and amides, respectively. The third chapter is the extension of the Suzuki-Miyuara reactions to phenyl ester derivatives of aspartic acid to synthesize aryl amino ketones. Chapter four describes the development of mild palladium-catalyzed Suzuki-Miyuara reactions of diaryl methyl 2,3,4,5,6-pentafluorobenzoates to synthesize triarylmethanes.The first appendix describes preliminary work on palladium-catalyzed benzylic decarboxylation reactions as a more atom economical method for the synthesis of diarylmethanes. The second appendix describes preliminary work on palladium-catalyzed Suzuki-Miyaura reactions of activated aziridines and stoichiometric reactions of phosphine ligated nickel complexes with activated aziridines.
590 $a School code: 0265.
650 4 $a Chemistry. $3 516420
650 4 $a Polymers. $3 535398
650 4 $a Oxidation. $3 714629
650 4 $a Palladium. $3 644757
650 4 $a Carbon. $3 604057
650 4 $a Solvents. $3 620946
650 4 $a Conversion. $3 630691
650 4 $a Amino acids. $3 558768
650 4 $a Ligands. $3 686413
650 4 $a Phenols. $3 915439
650 4 $a Electronics. $3 517156
650 4 $a Peptides. $3 605772
650 4 $a Nobel prizes. $3 647941
650 4 $a Influence. $3 1973172
650 4 $a Nitrogen. $3 1314426
650 4 $a Alzheimers disease. $3 3560855
653 $a Cross-coupling reactions
653 $a Precatalyst activation
653 $a Suzuk-Miyuara
653 $a Buchwald Hartwig
690 $a 0485
710 2 $a Yale University. $b Chemistry. $3 2101664
773 0 $t Dissertations Abstracts International $g 83-02B.
790 $a 0265
791 $a Ph.D.
792 $a 2021
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28258148