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Magnetic Resonance Studies of Energy...
~
Vazquez Reina, Rafael.
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Magnetic Resonance Studies of Energy Storage Materials.
紀錄類型:
書目-語言資料,印刷品 : Monograph/item
正題名/作者:
Magnetic Resonance Studies of Energy Storage Materials./
作者:
Vazquez Reina, Rafael.
面頁冊數:
113 p.
附註:
Source: Dissertation Abstracts International, Volume: 74-06(E), Section: B.
Contained By:
Dissertation Abstracts International74-06B(E).
標題:
Physics, Electricity and Magnetism. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3553256
ISBN:
9781267925862
Magnetic Resonance Studies of Energy Storage Materials.
Vazquez Reina, Rafael.
Magnetic Resonance Studies of Energy Storage Materials.
- 113 p.
Source: Dissertation Abstracts International, Volume: 74-06(E), Section: B.
Thesis (Ph.D.)--City University of New York, 2013.
In today's society there is high demand to have access to energy for portable devices in different forms. Capacitors with high performance in small package to achieve high charge/discharge rates, and batteries with their ability to store electricity and make energy mobile are part of this demand.
ISBN: 9781267925862Subjects--Topical Terms:
1019535
Physics, Electricity and Magnetism.
Magnetic Resonance Studies of Energy Storage Materials.
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Source: Dissertation Abstracts International, Volume: 74-06(E), Section: B.
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Adviser: Steven G. Greenbaum.
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Thesis (Ph.D.)--City University of New York, 2013.
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In today's society there is high demand to have access to energy for portable devices in different forms. Capacitors with high performance in small package to achieve high charge/discharge rates, and batteries with their ability to store electricity and make energy mobile are part of this demand.
520
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The types of internal dielectric material strongly affect the characteristics of a capacitor, and its applications. In a battery, the choice of the electrolyte plays an important role in the Solid Electrolyte Interphase (SEI) formation, and the cathode material for high output voltage.
520
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Electron Paramagnetic Resonance (EPR) and Nuclear Magnetic Resonance (NMR) spectroscopy are research techniques that exploit the magnetic properties of the electron and certain atomic nuclei to determine physical and chemical properties of the atoms or molecules in which they are contained. Both EPR and NMR spectroscopy technique can yield meaningful structural and dynamic information.
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Three different projects are discussed in this dissertation. First, High energy density capacitors where EPR measurements described herein provide an insight into structural and chemical differences in the dielectric material of a capacitor. Next, as the second project, Electrolyte solutions where an oxygen-17 NMR study has been employed to assess the degree of preferential solvation of Li+ ions in binary mixtures of EC (ethylene carbonate) and DMC (dimethyl carbonate) containing LiPF6 (lithium hexafluo-rophosphate) which may be ultimately related to the SEI formation mechanism. The third project was to study Bismuth fluoride as cathode material for rechargeable batteries. The objective was to study 19F and 7Li MAS NMR of some nanocomposite cathode materials as a conversion reaction occurring during lithiation and delithation of the BiF3/C nanocomposite.
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